Study of the effect of methods for liquid-phase synthesis of nanopowders on the structure and physicochemical properties of ceramics in the CeO2–Y2O3 system

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Study of the effect of methods for liquid-phase synthesis of nanopowders on the structure and physicochemical properties of ceramics in the CeO₂–Y₂O₃ system. / Egorova, T. L.; Kalinina, M. V.; Simonenko, E. P.; Simonenko, N. P.; Kopitsa, G. P.; Glumov, O. V.; Mel’nikova, N. A.; Murin, I. V.; Almásy, L.; Shilova, O. A.

в: Russian Journal of Inorganic Chemistry, Том 62, № 10, 01.10.2017, стр. 1275-1285.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Author

Egorova, T. L. ; Kalinina, M. V. ; Simonenko, E. P. ; Simonenko, N. P. ; Kopitsa, G. P. ; Glumov, O. V. ; Mel’nikova, N. A. ; Murin, I. V. ; Almásy, L. ; Shilova, O. A. / Study of the effect of methods for liquid-phase synthesis of nanopowders on the structure and physicochemical properties of ceramics in the CeO₂–Y₂O₃ system. в: Russian Journal of Inorganic Chemistry. 2017 ; Том 62, № 10. стр. 1275-1285.

BibTeX

@article{5d08783edb1f42eebf99ab52de619c59,

title = "Study of the effect of methods for liquid-phase synthesis of nanopowders on the structure and physicochemical properties of ceramics in the CeO2–Y2O3 system",

abstract = "Two alternative chemical synthesis methods—cryotechnological coprecipitation of hydroxides and cocrystallization of salts—were used for preparing (CeO2)1–x(Y2O3)x nanopowders (x = 0.10, 0.15, 0.20) with a mean coherent scattering domain size of ~7–11 nm and Ssp = 2.1–97.5 m2/g. From these nanopowders, ceramic nanomaterials with mean coherent scattering domain sizes of ~61–85 nm were synthesized. It was studied how the phase composition, microstructure, and electrical transport properties of the produced samples depend on the Y2O3 content of a CeO2-based solid solution and on the synthesis method. It was shown that, in the series (CeO2)1–x(Y2O3)x (x = 0.10, 0.15, 0.20), the solid solution (CeO2)0.90(Y2O3)0.10 has the highest ionic conductivity with the ion transport number ti = 0.73 (600°C). In its physicochemical characteristics, this ceramic can be used as a solid electrolyte of intermediate-temperature fuel cells.",

author = "Egorova, {T. L.} and Kalinina, {M. V.} and Simonenko, {E. P.} and Simonenko, {N. P.} and Kopitsa, {G. P.} and Glumov, {O. V.} and Mel{\textquoteright}nikova, {N. A.} and Murin, {I. V.} and L. Alm{\'a}sy and Shilova, {O. A.}",

year = "2017",

month = oct,

day = "1",

doi = "10.1134/S0036023617100072",

language = "English",

volume = "62",

pages = "1275--1285",

journal = "Russian Journal of Inorganic Chemistry",

issn = "0036-0236",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "10",

}

RIS

TY - JOUR

T1 - Study of the effect of methods for liquid-phase synthesis of nanopowders on the structure and physicochemical properties of ceramics in the CeO2–Y2O3 system

AU - Egorova, T. L.

AU - Kalinina, M. V.

AU - Simonenko, E. P.

AU - Simonenko, N. P.

AU - Kopitsa, G. P.

AU - Glumov, O. V.

AU - Mel’nikova, N. A.

AU - Murin, I. V.

AU - Almásy, L.

AU - Shilova, O. A.

PY - 2017/10/1

Y1 - 2017/10/1

N2 - Two alternative chemical synthesis methods—cryotechnological coprecipitation of hydroxides and cocrystallization of salts—were used for preparing (CeO2)1–x(Y2O3)x nanopowders (x = 0.10, 0.15, 0.20) with a mean coherent scattering domain size of ~7–11 nm and Ssp = 2.1–97.5 m2/g. From these nanopowders, ceramic nanomaterials with mean coherent scattering domain sizes of ~61–85 nm were synthesized. It was studied how the phase composition, microstructure, and electrical transport properties of the produced samples depend on the Y2O3 content of a CeO2-based solid solution and on the synthesis method. It was shown that, in the series (CeO2)1–x(Y2O3)x (x = 0.10, 0.15, 0.20), the solid solution (CeO2)0.90(Y2O3)0.10 has the highest ionic conductivity with the ion transport number ti = 0.73 (600°C). In its physicochemical characteristics, this ceramic can be used as a solid electrolyte of intermediate-temperature fuel cells.

AB - Two alternative chemical synthesis methods—cryotechnological coprecipitation of hydroxides and cocrystallization of salts—were used for preparing (CeO2)1–x(Y2O3)x nanopowders (x = 0.10, 0.15, 0.20) with a mean coherent scattering domain size of ~7–11 nm and Ssp = 2.1–97.5 m2/g. From these nanopowders, ceramic nanomaterials with mean coherent scattering domain sizes of ~61–85 nm were synthesized. It was studied how the phase composition, microstructure, and electrical transport properties of the produced samples depend on the Y2O3 content of a CeO2-based solid solution and on the synthesis method. It was shown that, in the series (CeO2)1–x(Y2O3)x (x = 0.10, 0.15, 0.20), the solid solution (CeO2)0.90(Y2O3)0.10 has the highest ionic conductivity with the ion transport number ti = 0.73 (600°C). In its physicochemical characteristics, this ceramic can be used as a solid electrolyte of intermediate-temperature fuel cells.

UR - http://www.scopus.com/inward/record.url?scp=85032011684&partnerID=8YFLogxK

U2 - 10.1134/S0036023617100072

DO - 10.1134/S0036023617100072

M3 - Article

AN - SCOPUS:85032011684

VL - 62

SP - 1275

EP - 1285

JO - Russian Journal of Inorganic Chemistry

JF - Russian Journal of Inorganic Chemistry

SN - 0036-0236

IS - 10

ER -

ID: 9436057