TY - CHAP

T1 - Structure-Directing (Cyanamide)···Arene Noncovalent Interactions in Cocrystals of Copper(II) Clusters with Arenes

AU - Toikka , Yulia

A2 - Bokach , N.A.

PY - 2020

Y1 - 2020

N2 - Polynuclear clusters and noncovalent interactions play an important role in determining the structure, properties, and reactivity of organic and organometallic species. In this report crystallization of newly prepared copper(II) tetranuclear clusters [Cu4X6O(NCNMe2)4] (X = Cl 1, Br 2) and their adducts from toluene and styrene solutions afforded crystalline substances: 1·4PhMe, 1·4PhCH=CH2, 2·4PhMe, and 2·4PhCH=CH2, which were characterized by physicochemical methods including XRD, IR and AAS. Inspection of the X-ray structures of (1−2)·4(arene) and the appropriate Hirshfeld molecular surface analysis allowed the recognition of the previously unreported π-hole···arene interactions involving the cyanamide ligands.

AB - Polynuclear clusters and noncovalent interactions play an important role in determining the structure, properties, and reactivity of organic and organometallic species. In this report crystallization of newly prepared copper(II) tetranuclear clusters [Cu4X6O(NCNMe2)4] (X = Cl 1, Br 2) and their adducts from toluene and styrene solutions afforded crystalline substances: 1·4PhMe, 1·4PhCH=CH2, 2·4PhMe, and 2·4PhCH=CH2, which were characterized by physicochemical methods including XRD, IR and AAS. Inspection of the X-ray structures of (1−2)·4(arene) and the appropriate Hirshfeld molecular surface analysis allowed the recognition of the previously unreported π-hole···arene interactions involving the cyanamide ligands.

UR - https://events.spbu.ru/eventsContent/events/2020/S&P2020.pdf

M3 - Conference abstracts

SN - 978-5-85263-224-1

SP - 101

BT - International Student Conference “Science and Progress”

PB - ООО "Сборка"

CY - СПб.

T2 - International Student Conference Science and Progress 2020

Y2 - 10 November 2020 through 12 November 2020

ER -