Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Structure of 2-chloro-3-phenylbenzoic acid. / Boyarskiy, V. P.; Fonari, M. S.; Suwinska, K.; Simonov, Yu A.
в: Journal of Structural Chemistry, Том 50, № 3, 07.2009, стр. 585-587.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Structure of 2-chloro-3-phenylbenzoic acid
AU - Boyarskiy, V. P.
AU - Fonari, M. S.
AU - Suwinska, K.
AU - Simonov, Yu A.
N1 - Funding Information: The work was supported by RFBR and the Academy of Sciences of the Republic of Moldova, Project 08-03-90104
PY - 2009/7
Y1 - 2009/7
N2 - The carbonylation reaction of 2,3-dichlorobiphenyl proceeds with a substitution of the chlorine atom in position 3 and results in the formation of 2-chloro-3-phenylbenzoic acid. The structure of this acid is revealed by single crystal XRD. It is determined by steric interactions of substituents in positions 2,4,2′, and 6′, a stable carboxyl supramolecular synthon, and weak interactions with the participation of the carbonyl oxygen atom and the chlorine atom.
AB - The carbonylation reaction of 2,3-dichlorobiphenyl proceeds with a substitution of the chlorine atom in position 3 and results in the formation of 2-chloro-3-phenylbenzoic acid. The structure of this acid is revealed by single crystal XRD. It is determined by steric interactions of substituents in positions 2,4,2′, and 6′, a stable carboxyl supramolecular synthon, and weak interactions with the participation of the carbonyl oxygen atom and the chlorine atom.
KW - Aromatic carbonic acids
KW - Carbonylation
KW - Crystal structure
KW - Polychlorobiphenyls
KW - Synthesis
UR - http://www.scopus.com/inward/record.url?scp=70350681103&partnerID=8YFLogxK
U2 - 10.1007/s10947-009-0091-2
DO - 10.1007/s10947-009-0091-2
M3 - Article
AN - SCOPUS:70350681103
VL - 50
SP - 585
EP - 587
JO - Journal of Structural Chemistry
JF - Journal of Structural Chemistry
SN - 0022-4766
IS - 3
ER -
ID: 87472131