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Structure and Stability of Hydrogen Compounds of Group 13/15 Elements Stabilized with Lewis Acids and Bases. / Pomogaeva, A. V. ; Lisovenko, A. S. ; Timoshkin, A. Y. .

в: Russian Journal of General Chemistry, Том 93, № 4, 25.05.2023, стр. 900-908.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Pomogaeva, AV, Lisovenko, AS & Timoshkin, AY 2023, 'Structure and Stability of Hydrogen Compounds of Group 13/15 Elements Stabilized with Lewis Acids and Bases', Russian Journal of General Chemistry, Том. 93, № 4, стр. 900-908. https://doi.org/10.1134/s1070363223040175

APA

Pomogaeva, A. V., Lisovenko, A. S., & Timoshkin, A. Y. (2023). Structure and Stability of Hydrogen Compounds of Group 13/15 Elements Stabilized with Lewis Acids and Bases. Russian Journal of General Chemistry, 93(4), 900-908. https://doi.org/10.1134/s1070363223040175

Vancouver

Pomogaeva AV, Lisovenko AS, Timoshkin AY. Structure and Stability of Hydrogen Compounds of Group 13/15 Elements Stabilized with Lewis Acids and Bases. Russian Journal of General Chemistry. 2023 Май 25;93(4):900-908. https://doi.org/10.1134/s1070363223040175

Author

Pomogaeva, A. V. ; Lisovenko, A. S. ; Timoshkin, A. Y. . / Structure and Stability of Hydrogen Compounds of Group 13/15 Elements Stabilized with Lewis Acids and Bases. в: Russian Journal of General Chemistry. 2023 ; Том 93, № 4. стр. 900-908.

BibTeX

@article{5d05c1095b8c4eeda58338112b93049d,
title = "Structure and Stability of Hydrogen Compounds of Group 13/15 Elements Stabilized with Lewis Acids and Bases",
abstract = "Structural and thermodynamic characteristics of donor-acceptor complexes LA·E′H2EH2·LB were computed by the B3LYP-D3/def2-TZVP quantum chemical method [E = B, Al, Ga; E′ = P, As, Sb; LA are Lewis acids of group 13 elements ER3 (R = H, Me, F, Cl, Br, I, C6F5) and transition metal carbonyls Fe(CO)4, M(CO)5 (M = Cr, Mo, W), CpMn(CO)2; Lewis bases LB = NMe3, SMe2]. It was shown that removal of a Lewis base is less endothermic than removal of a Lewis acid. Stability trends of the complexes depending on the nature of group 13/15 elements and Lewis acids were established. Pentacarbonyltungsten has the highest stabilization effect.",
keywords = "group 13/15 element hydrides, Lewis acids, Lewis bases, donor-acceptor bond, quantum chemical calculations, group 13/15 element hydrides, Lewis acids, Lewis bases, donor-acceptor bond, quantum chemical calculations, group 13/15 element hydrides, donor-acceptor bond, Lewis acids, quantum chemical calculations, Lewis bases",
author = "Pomogaeva, {A. V.} and Lisovenko, {A. S.} and Timoshkin, {A. Y.}",
note = "Pomogaeva, A.V., Lisovenko, A.S. & Timoshkin, A.Y. Structure and Stability of Hydrogen Compounds of Group 13/15 Elements Stabilized with Lewis Acids and Bases. Russ J Gen Chem 93, 900–908 (2023). https://doi.org/10.1134/S1070363223040175",
year = "2023",
month = may,
day = "25",
doi = "10.1134/s1070363223040175",
language = "English",
volume = "93",
pages = "900--908",
journal = "Russian Journal of General Chemistry",
issn = "1070-3632",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "4",

}

RIS

TY - JOUR

T1 - Structure and Stability of Hydrogen Compounds of Group 13/15 Elements Stabilized with Lewis Acids and Bases

AU - Pomogaeva, A. V.

AU - Lisovenko, A. S.

AU - Timoshkin, A. Y.

N1 - Pomogaeva, A.V., Lisovenko, A.S. & Timoshkin, A.Y. Structure and Stability of Hydrogen Compounds of Group 13/15 Elements Stabilized with Lewis Acids and Bases. Russ J Gen Chem 93, 900–908 (2023). https://doi.org/10.1134/S1070363223040175

PY - 2023/5/25

Y1 - 2023/5/25

N2 - Structural and thermodynamic characteristics of donor-acceptor complexes LA·E′H2EH2·LB were computed by the B3LYP-D3/def2-TZVP quantum chemical method [E = B, Al, Ga; E′ = P, As, Sb; LA are Lewis acids of group 13 elements ER3 (R = H, Me, F, Cl, Br, I, C6F5) and transition metal carbonyls Fe(CO)4, M(CO)5 (M = Cr, Mo, W), CpMn(CO)2; Lewis bases LB = NMe3, SMe2]. It was shown that removal of a Lewis base is less endothermic than removal of a Lewis acid. Stability trends of the complexes depending on the nature of group 13/15 elements and Lewis acids were established. Pentacarbonyltungsten has the highest stabilization effect.

AB - Structural and thermodynamic characteristics of donor-acceptor complexes LA·E′H2EH2·LB were computed by the B3LYP-D3/def2-TZVP quantum chemical method [E = B, Al, Ga; E′ = P, As, Sb; LA are Lewis acids of group 13 elements ER3 (R = H, Me, F, Cl, Br, I, C6F5) and transition metal carbonyls Fe(CO)4, M(CO)5 (M = Cr, Mo, W), CpMn(CO)2; Lewis bases LB = NMe3, SMe2]. It was shown that removal of a Lewis base is less endothermic than removal of a Lewis acid. Stability trends of the complexes depending on the nature of group 13/15 elements and Lewis acids were established. Pentacarbonyltungsten has the highest stabilization effect.

KW - group 13/15 element hydrides, Lewis acids, Lewis bases, donor-acceptor bond, quantum chemical calculations

KW - group 13/15 element hydrides, Lewis acids, Lewis bases, donor-acceptor bond, quantum chemical calculations

KW - group 13/15 element hydrides

KW - donor-acceptor bond

KW - Lewis acids

KW - quantum chemical calculations

KW - Lewis bases

UR - https://www.mendeley.com/catalogue/3b69ca37-6735-377a-bb2a-c5297ab30d70/

U2 - 10.1134/s1070363223040175

DO - 10.1134/s1070363223040175

M3 - Article

VL - 93

SP - 900

EP - 908

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 4

ER -

ID: 105514958