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Structure and Properties of Macromolecules with Side Dendrons Based on L-Aspartic Acid. / Tsvetkov, N. V.; Andreeva, L. N.; Bushin, S. V.; Strelina, I. A.; Bezrukova, M. A.; Girbasova, N. V.; Bilibin, A. Yu.

в: Polymer Science - Series C, Том 52, № 1, 2010, стр. 3-16.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Tsvetkov, NV, Andreeva, LN, Bushin, SV, Strelina, IA, Bezrukova, MA, Girbasova, NV & Bilibin, AY 2010, 'Structure and Properties of Macromolecules with Side Dendrons Based on L-Aspartic Acid', Polymer Science - Series C, Том. 52, № 1, стр. 3-16. https://doi.org/10.1134/S1811238210010029

APA

Tsvetkov, N. V., Andreeva, L. N., Bushin, S. V., Strelina, I. A., Bezrukova, M. A., Girbasova, N. V., & Bilibin, A. Y. (2010). Structure and Properties of Macromolecules with Side Dendrons Based on L-Aspartic Acid. Polymer Science - Series C, 52(1), 3-16. https://doi.org/10.1134/S1811238210010029

Vancouver

Tsvetkov NV, Andreeva LN, Bushin SV, Strelina IA, Bezrukova MA, Girbasova NV и пр. Structure and Properties of Macromolecules with Side Dendrons Based on L-Aspartic Acid. Polymer Science - Series C. 2010;52(1):3-16. https://doi.org/10.1134/S1811238210010029

Author

Tsvetkov, N. V. ; Andreeva, L. N. ; Bushin, S. V. ; Strelina, I. A. ; Bezrukova, M. A. ; Girbasova, N. V. ; Bilibin, A. Yu. / Structure and Properties of Macromolecules with Side Dendrons Based on L-Aspartic Acid. в: Polymer Science - Series C. 2010 ; Том 52, № 1. стр. 3-16.

BibTeX

@article{184d0138d41e4485a113d1135f821833,
title = "Structure and Properties of Macromolecules with Side Dendrons Based on L-Aspartic Acid",
abstract = "The molecular characteristics of cylindrical first–third generation dendrimers carrying dendrons based on L-aspartic acid are compared. It is shown that both the generation number of side dendrons and their structure determine the conformational, hydrodynamic, optical, and dipole characteristics of dendrite macromolecules. It is found that the studied class of cylindrical dendrimers is distinguished by a marked amount of intramolecular hydrogen bonds between side dendrite substituents. These bonds ensure the unusual combination of high kinetic rigidity and a compact conformation (low equilibrium rigidity) of macromolecules. The rupture of hydrogen bonds leads to an enlargement of molecular coils (an increase in equilibrium rigidity) that is accompanied by a sharp drop in kinetic rigidity.",
author = "Tsvetkov, {N. V.} and Andreeva, {L. N.} and Bushin, {S. V.} and Strelina, {I. A.} and Bezrukova, {M. A.} and Girbasova, {N. V.} and Bilibin, {A. Yu.}",
year = "2010",
doi = "10.1134/S1811238210010029",
language = "English",
volume = "52",
pages = "3--16",
journal = "Polymer Science - Series C",
issn = "1811-2382",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "1",

}

RIS

TY - JOUR

T1 - Structure and Properties of Macromolecules with Side Dendrons Based on L-Aspartic Acid

AU - Tsvetkov, N. V.

AU - Andreeva, L. N.

AU - Bushin, S. V.

AU - Strelina, I. A.

AU - Bezrukova, M. A.

AU - Girbasova, N. V.

AU - Bilibin, A. Yu.

PY - 2010

Y1 - 2010

N2 - The molecular characteristics of cylindrical first–third generation dendrimers carrying dendrons based on L-aspartic acid are compared. It is shown that both the generation number of side dendrons and their structure determine the conformational, hydrodynamic, optical, and dipole characteristics of dendrite macromolecules. It is found that the studied class of cylindrical dendrimers is distinguished by a marked amount of intramolecular hydrogen bonds between side dendrite substituents. These bonds ensure the unusual combination of high kinetic rigidity and a compact conformation (low equilibrium rigidity) of macromolecules. The rupture of hydrogen bonds leads to an enlargement of molecular coils (an increase in equilibrium rigidity) that is accompanied by a sharp drop in kinetic rigidity.

AB - The molecular characteristics of cylindrical first–third generation dendrimers carrying dendrons based on L-aspartic acid are compared. It is shown that both the generation number of side dendrons and their structure determine the conformational, hydrodynamic, optical, and dipole characteristics of dendrite macromolecules. It is found that the studied class of cylindrical dendrimers is distinguished by a marked amount of intramolecular hydrogen bonds between side dendrite substituents. These bonds ensure the unusual combination of high kinetic rigidity and a compact conformation (low equilibrium rigidity) of macromolecules. The rupture of hydrogen bonds leads to an enlargement of molecular coils (an increase in equilibrium rigidity) that is accompanied by a sharp drop in kinetic rigidity.

U2 - 10.1134/S1811238210010029

DO - 10.1134/S1811238210010029

M3 - Article

VL - 52

SP - 3

EP - 16

JO - Polymer Science - Series C

JF - Polymer Science - Series C

SN - 1811-2382

IS - 1

ER -

ID: 5205722