Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Structural and luminescence properties of Ce3+-doped hydroxyapatite nanocrystalline powders. / Kolesnikov, I. E.; Nikolaev, A. M.; Lähderanta, E.; Frank-Kamenetskaya, O. V.; Kuz'mina, M. A.
в: Optical Materials, 01.01.2020.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Structural and luminescence properties of Ce3+-doped hydroxyapatite nanocrystalline powders
AU - Kolesnikov, I. E.
AU - Nikolaev, A. M.
AU - Lähderanta, E.
AU - Frank-Kamenetskaya, O. V.
AU - Kuz'mina, M. A.
PY - 2020/1/1
Y1 - 2020/1/1
N2 - Ce3+-doped apatites have been synthesized by precipitation method in the range of the Ce/Ca atomic ratio in solutions from 0.05 to 5%. Obtained precipitates were studied with X-ray powder diffraction, infrared spectroscopy, scanning electron microscopy, EDX and luminescence spectroscopy. Cerium content in the synthesized apatites reaches 0.33 apfu (Ce/Ca = 3.9%). Relations between Ce content in the solution and precipitate have been established. It was revealed that during synthesis Ce-monazite starts to precipitate as a secondary phase at 1% Ce/Ca ratio in starting solution. Doping concentration effect on the luminescence intensity and lifetime of HAp:Ce3+ nanophosphors was studied in detail. Optimum doping concentration of Ce3+ ions in hydroxyapatite host was determined to be 0.3% of the Ce/Ca atomic ratio, which corresponds to 0.5% of the Ce/Ca ratio in the starting solution. The luminescence quenching occurs through energy transfer among the nearest neighbor Ce3+ ions.
AB - Ce3+-doped apatites have been synthesized by precipitation method in the range of the Ce/Ca atomic ratio in solutions from 0.05 to 5%. Obtained precipitates were studied with X-ray powder diffraction, infrared spectroscopy, scanning electron microscopy, EDX and luminescence spectroscopy. Cerium content in the synthesized apatites reaches 0.33 apfu (Ce/Ca = 3.9%). Relations between Ce content in the solution and precipitate have been established. It was revealed that during synthesis Ce-monazite starts to precipitate as a secondary phase at 1% Ce/Ca ratio in starting solution. Doping concentration effect on the luminescence intensity and lifetime of HAp:Ce3+ nanophosphors was studied in detail. Optimum doping concentration of Ce3+ ions in hydroxyapatite host was determined to be 0.3% of the Ce/Ca atomic ratio, which corresponds to 0.5% of the Ce/Ca ratio in the starting solution. The luminescence quenching occurs through energy transfer among the nearest neighbor Ce3+ ions.
KW - Ce
KW - Hydroxyapatite
KW - Lifetime
KW - Luminescence
KW - Quenching
UR - http://www.scopus.com/inward/record.url?scp=85075878959&partnerID=8YFLogxK
U2 - 10.1016/j.optmat.2019.109550
DO - 10.1016/j.optmat.2019.109550
M3 - Article
AN - SCOPUS:85075878959
JO - Optical Materials
JF - Optical Materials
SN - 0925-3467
M1 - 109550
ER -
ID: 49775978