TY - JOUR

T1 - Strong halogen bonds with guest molecules in Co(II) 2,5-diiodoterephthalate metal-organic framework

AU - Zaguzin, Alexander S

AU - Zaitsev, Artem V

AU - Abramov, Pavel A

AU - Novikov, Alexander S.

AU - Fedin, Vladimir P

AU - Adonin, Sergey A

PY - 2025/6/12

Y1 - 2025/6/12

N2 - Two heteroleptic Co(II) 2,5-diiodoisoterephthalates (2,5-I-bdc) with 1,2-bis(4-pyridyl)ethane (bpe) linker, both of {[Co(2,5-I-bdc)bpe]·XDMF}n formulae (1 and 2), were prepared. In the structure of 2, guest DMF molecules form a prominent halogen...Two heteroleptic Co(II) 2,5-diiodoisoterephthalates (2,5-I-bdc) with 1,2-bis(4-pyridyl)ethane (bpe) linker, both of {[Co(2,5-I-bdc)bpe]·XDMF}n formulae (1 and 2), were prepared. In the structure of 2, guest DMF molecules form a prominent halogen bond with iodine atoms of dicarboxylate ligand. The energies of these interactons were estimated from the bond critical point characteristics (QTAIM analysis).

AB - Two heteroleptic Co(II) 2,5-diiodoisoterephthalates (2,5-I-bdc) with 1,2-bis(4-pyridyl)ethane (bpe) linker, both of {[Co(2,5-I-bdc)bpe]·XDMF}n formulae (1 and 2), were prepared. In the structure of 2, guest DMF molecules form a prominent halogen...Two heteroleptic Co(II) 2,5-diiodoisoterephthalates (2,5-I-bdc) with 1,2-bis(4-pyridyl)ethane (bpe) linker, both of {[Co(2,5-I-bdc)bpe]·XDMF}n formulae (1 and 2), were prepared. In the structure of 2, guest DMF molecules form a prominent halogen bond with iodine atoms of dicarboxylate ligand. The energies of these interactons were estimated from the bond critical point characteristics (QTAIM analysis).

UR - https://www.mendeley.com/catalogue/eee171d0-8aff-3846-accb-c7a6e1dd76fe/

U2 - 10.1039/d5ce00440c

DO - 10.1039/d5ce00440c

M3 - Article

JO - CrystEngComm

JF - CrystEngComm

SN - 1466-8033

ER -