Standard

Splitting of the 1s-1 3p resonance in sulfur K XANES by surroundings in compounds with sulfurcarbon double bond. / Hallmeier, K. H.; Pavlychev, A. A.; Szargan, R.; Beyer, L.; Hennig, C.; Thiel, F.

в: Chemical Physics, Том 178, № 1-3, 15.12.1993, стр. 349-356.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Hallmeier, KH, Pavlychev, AA, Szargan, R, Beyer, L, Hennig, C & Thiel, F 1993, 'Splitting of the 1s-1 3p resonance in sulfur K XANES by surroundings in compounds with sulfurcarbon double bond', Chemical Physics, Том. 178, № 1-3, стр. 349-356. https://doi.org/10.1016/0301-0104(93)85073-H

APA

Hallmeier, K. H., Pavlychev, A. A., Szargan, R., Beyer, L., Hennig, C., & Thiel, F. (1993). Splitting of the 1s-1 3p resonance in sulfur K XANES by surroundings in compounds with sulfurcarbon double bond. Chemical Physics, 178(1-3), 349-356. https://doi.org/10.1016/0301-0104(93)85073-H

Vancouver

Hallmeier KH, Pavlychev AA, Szargan R, Beyer L, Hennig C, Thiel F. Splitting of the 1s-1 3p resonance in sulfur K XANES by surroundings in compounds with sulfurcarbon double bond. Chemical Physics. 1993 Дек. 15;178(1-3):349-356. https://doi.org/10.1016/0301-0104(93)85073-H

Author

Hallmeier, K. H. ; Pavlychev, A. A. ; Szargan, R. ; Beyer, L. ; Hennig, C. ; Thiel, F. / Splitting of the 1s-1 3p resonance in sulfur K XANES by surroundings in compounds with sulfurcarbon double bond. в: Chemical Physics. 1993 ; Том 178, № 1-3. стр. 349-356.

BibTeX

@article{a6a56f9b171d48cdbb8ddf0b96d8cf48,
title = "Splitting of the 1s-1 3p resonance in sulfur K XANES by surroundings in compounds with sulfurcarbon double bond",
abstract = "Results of the experimental and theoretical investigation of X-ray absorption S K near-edge structure in complex compounds containing a sulfurcarbon double bond mostly in the thioureato group are presented. In the framework of a quasi-atomic model the splitting of the 1s-13p resonance of the sulfur atom has been found to dominate the S K XANES. The splitting of this resonance into three (one π* and two σ*) components allows to explain the main features in the spectral density of oscillator strengths of transitions from the S K-shell. To describe the splitting both the resonance effects inside the SCN2 group and the influence of atoms located in opposition to the sulfur atom have to be taken into account. Applying the quasi-atomic approximation the variation of the partial charge on the sulfur atom in the compounds is analyzed.",
author = "Hallmeier, {K. H.} and Pavlychev, {A. A.} and R. Szargan and L. Beyer and C. Hennig and F. Thiel",
year = "1993",
month = dec,
day = "15",
doi = "10.1016/0301-0104(93)85073-H",
language = "English",
volume = "178",
pages = "349--356",
journal = "Chemical Physics",
issn = "0301-0104",
publisher = "Elsevier",
number = "1-3",

}

RIS

TY - JOUR

T1 - Splitting of the 1s-1 3p resonance in sulfur K XANES by surroundings in compounds with sulfurcarbon double bond

AU - Hallmeier, K. H.

AU - Pavlychev, A. A.

AU - Szargan, R.

AU - Beyer, L.

AU - Hennig, C.

AU - Thiel, F.

PY - 1993/12/15

Y1 - 1993/12/15

N2 - Results of the experimental and theoretical investigation of X-ray absorption S K near-edge structure in complex compounds containing a sulfurcarbon double bond mostly in the thioureato group are presented. In the framework of a quasi-atomic model the splitting of the 1s-13p resonance of the sulfur atom has been found to dominate the S K XANES. The splitting of this resonance into three (one π* and two σ*) components allows to explain the main features in the spectral density of oscillator strengths of transitions from the S K-shell. To describe the splitting both the resonance effects inside the SCN2 group and the influence of atoms located in opposition to the sulfur atom have to be taken into account. Applying the quasi-atomic approximation the variation of the partial charge on the sulfur atom in the compounds is analyzed.

AB - Results of the experimental and theoretical investigation of X-ray absorption S K near-edge structure in complex compounds containing a sulfurcarbon double bond mostly in the thioureato group are presented. In the framework of a quasi-atomic model the splitting of the 1s-13p resonance of the sulfur atom has been found to dominate the S K XANES. The splitting of this resonance into three (one π* and two σ*) components allows to explain the main features in the spectral density of oscillator strengths of transitions from the S K-shell. To describe the splitting both the resonance effects inside the SCN2 group and the influence of atoms located in opposition to the sulfur atom have to be taken into account. Applying the quasi-atomic approximation the variation of the partial charge on the sulfur atom in the compounds is analyzed.

UR - http://www.scopus.com/inward/record.url?scp=21344479342&partnerID=8YFLogxK

U2 - 10.1016/0301-0104(93)85073-H

DO - 10.1016/0301-0104(93)85073-H

M3 - Article

AN - SCOPUS:21344479342

VL - 178

SP - 349

EP - 356

JO - Chemical Physics

JF - Chemical Physics

SN - 0301-0104

IS - 1-3

ER -

ID: 43210941