Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Spectroscopic studies of ozone in cryosolutions : FT-IR spectra of O-16(3) in liquid nitrogen, oxygen, argon and krypton. / Bulanin, Kirill M.; Bulanin, Michael O.; Rudakova, Aida V.; Kolomijtsova, Tatiana D.; Shchepkin, Dmitrij N.
в: SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, Том 193, 15.03.2018, стр. 385-392.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Spectroscopic studies of ozone in cryosolutions
T2 - FT-IR spectra of O-16(3) in liquid nitrogen, oxygen, argon and krypton
AU - Bulanin, Kirill M.
AU - Bulanin, Michael O.
AU - Rudakova, Aida V.
AU - Kolomijtsova, Tatiana D.
AU - Shchepkin, Dmitrij N.
PY - 2018/3/15
Y1 - 2018/3/15
N2 - We have measured and interpreted the IR spectra of ozone dissolved in liquid nitrogen, oxygen, argon, and krypton in the 650-4700 cm(-1) spectral region at 79-117 K. Frequency shifts, band intensities and bandshapes of 22 spectral features of soluted ozone were analyzed. The bands of the A(1) symmetry have a complex contour and possess an excess intensity with respect to the value of the purely vibrational transition moment. It was found that this effect is related to the manifestation of the Coriolis interaction. The bandshape distortion manifests itself as an additional intensity from the side of the B-1 symmetry band being an intensity source in the case of the Coriolis interaction. (C) 2017 Published by Elsevier B.V.
AB - We have measured and interpreted the IR spectra of ozone dissolved in liquid nitrogen, oxygen, argon, and krypton in the 650-4700 cm(-1) spectral region at 79-117 K. Frequency shifts, band intensities and bandshapes of 22 spectral features of soluted ozone were analyzed. The bands of the A(1) symmetry have a complex contour and possess an excess intensity with respect to the value of the purely vibrational transition moment. It was found that this effect is related to the manifestation of the Coriolis interaction. The bandshape distortion manifests itself as an additional intensity from the side of the B-1 symmetry band being an intensity source in the case of the Coriolis interaction. (C) 2017 Published by Elsevier B.V.
KW - LINE POSITIONS
KW - ABSOLUTE INTENSITIES
KW - ABSORPTION-SPECTRUM
KW - INFRARED-SPECTRA
KW - INERT MATRICES
KW - BANDS
KW - MOLECULE
KW - O-3
KW - COMPLEX
KW - REGION
UR - http://www.scopus.com/inward/record.url?scp=85038390731&partnerID=8YFLogxK
UR - http://www.mendeley.com/research/spectroscopic-studies-ozone-cryosolutions-ftir-spectra-of16o3in-liquid-nitrogen-oxygen-argon-krypton
U2 - 10.1016/j.saa.2017.11.037
DO - 10.1016/j.saa.2017.11.037
M3 - статья
VL - 193
SP - 385
EP - 392
JO - SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
JF - SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
SN - 1386-1425
ER -
ID: 36686228