Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Sorption of NdF3 and ThF4 from the LiF–NaF–KF Melt. / Fedorov, Yu S.; Samonin, V. V.; Zotov, A. S.; Khrylova, E. D.; Spiridonova, E. A.; Miroslavov, A. E.; Akatov, A. A.
в: Radiochemistry, Том 63, № 6, 01.06.2021, стр. 754-761.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Sorption of NdF3 and ThF4 from the LiF–NaF–KF Melt
AU - Fedorov, Yu S.
AU - Samonin, V. V.
AU - Zotov, A. S.
AU - Khrylova, E. D.
AU - Spiridonova, E. A.
AU - Miroslavov, A. E.
AU - Akatov, A. A.
PY - 2021/6/1
Y1 - 2021/6/1
N2 - Abstract: The sorption of neodymium and thorium fluorides by AG-3 activated carbon from molten alkali metal fluorides LiF–NaF–KF has been studied. The sorption isotherm of neodymium fluoride at 650°C has a pronounced convex and is adequately described by the Langmuir equation. The sorption of thorium fluoride under the same conditions is much weaker than that of neodymium fluoride, which is determined by the size of the neodymium and thorium fluoride complexes. The kinetic dependence of the sorption of neodymium fluoride at a temperature of 650°С is adequately described by a first-order equation for a reversible reaction. The temperature dependence of sorption capacity in the range 550–750°С passes a maximum within 600–650°С.
AB - Abstract: The sorption of neodymium and thorium fluorides by AG-3 activated carbon from molten alkali metal fluorides LiF–NaF–KF has been studied. The sorption isotherm of neodymium fluoride at 650°C has a pronounced convex and is adequately described by the Langmuir equation. The sorption of thorium fluoride under the same conditions is much weaker than that of neodymium fluoride, which is determined by the size of the neodymium and thorium fluoride complexes. The kinetic dependence of the sorption of neodymium fluoride at a temperature of 650°С is adequately described by a first-order equation for a reversible reaction. The temperature dependence of sorption capacity in the range 550–750°С passes a maximum within 600–650°С.
KW - activated carbon
KW - alkali metals
KW - fluorides
KW - melts
KW - neodymium
KW - sorption
KW - thorium
UR - http://www.scopus.com/inward/record.url?scp=85123503582&partnerID=8YFLogxK
U2 - 10.1134/S1066362221060072
DO - 10.1134/S1066362221060072
M3 - Article
AN - SCOPUS:85123503582
VL - 63
SP - 754
EP - 761
JO - Radiochemistry
JF - Radiochemistry
SN - 1066-3622
IS - 6
ER -
ID: 102709872