DOI

  • Päivi Mäki-Arvela
  • Jeanne Zhu
  • Narendra Kumar
  • Kari Eränen
  • Atte Aho
  • Johan Linden
  • Jarno Salonen
  • Markus Peurla
  • Anton Mazur
  • Vladimir Matveev
  • Dmitry Yu Murzin

Stearoyl ethanolamine was synthesized by amidation of stearic acid with ethanolamine in solventless conditions. Iron containing heterogeneous catalysts supported on SiO2, Al2O3, Beta (BEA), ZSM-12 (MTW) and Ferrierite (FER) were used in this work. Sn-modified Ferrierite and H-Ferrierite were also studied for comparison. Fe-modified catalysts synthesized using solid state ion-exchange and evaporation impregnation methods, were thoroughly characterized with X-ray powder diffraction, scanning electron microscope, FTIR with pyridine, nitrogen adsorption, energy dispersive X-ray microanalysis and Mössbauer spectroscopy. The highest conversion was obtained with Fe-H-FER-20 at 140 °C in 1 h giving 61% conversion and 98% selectivity towards the desired amide. The catalytic performance in terms of turnover frequency per mole of iron was achieved with the catalyst exhibiting the largest amount of Fe3+ species, optimum acidity and a relatively low Brønsted to Lewis acid site ratio.

Язык оригиналаанглийский
Страницы (с-по)350-358
Число страниц9
ЖурналApplied Catalysis A: General
Том542
DOI
СостояниеОпубликовано - 1 янв 2017

    Предметные области Scopus

  • Катализ
  • Химия и технология процессов

ID: 35749281