Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Solubility of d-Element Salts in Organic and Aqueous–Organic Solvents : VI. 1 Structure and Thermal Stability of Cadmium Iodide and Bromide Solvates with Dimethylacetamide and Dimethylformamide. / Богачев, Никита Александрович; Никольский, Алексей Борисович; Скрипкин, Михаил Юрьевич; Старова, Галина Леонидовна; Разживин, Александр Владимирович.
в: Russian Journal of General Chemistry, Том 88, № 1, 01.2018, стр. 1-6.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Solubility of d-Element Salts in Organic and Aqueous–Organic Solvents
T2 - VI. 1 Structure and Thermal Stability of Cadmium Iodide and Bromide Solvates with Dimethylacetamide and Dimethylformamide
AU - Богачев, Никита Александрович
AU - Никольский, Алексей Борисович
AU - Скрипкин, Михаил Юрьевич
AU - Старова, Галина Леонидовна
AU - Разживин, Александр Владимирович
N1 - Funding Information: This work was financially supported by the Russian Foundation for basic research (project no. 15-03-05139). The equipment of the Research park of St. Petersburg State University (Center for X-ray Diffraction Studies and Centre for Thermogravimetric and Calorimetric Research) was used.
PY - 2018/1
Y1 - 2018/1
N2 - Five solvates, [CdBr 2(DMF)] n, [CdBr 2(DMA)] n, [CdI 2(DMF)] n, [Cd(DMF) 6][Cd 2I 6], and {[Cd(DMA) 6][Cd 5I 12] n} m, were isolated from the ternary systems CdX 2–L–H 2O (X = Br, I; L = N,N-dimethylacetamide, N,N-dimethylformamide) and characterized by the X-ray single crystal analysis. The structures of the first three solvates is similar to each other in structures and represent a one-dimensional polymer chain, the fourth solvate has the discrete structure containing [Cd(DMF) 6] 2+ and [Cd 2I 6] 2– ions, and the fifth solvate contains discrete [Cd(DMA) 6] 2+ cations and the polymer anionic fragment [Cd 5I 12] n 2n–.
AB - Five solvates, [CdBr 2(DMF)] n, [CdBr 2(DMA)] n, [CdI 2(DMF)] n, [Cd(DMF) 6][Cd 2I 6], and {[Cd(DMA) 6][Cd 5I 12] n} m, were isolated from the ternary systems CdX 2–L–H 2O (X = Br, I; L = N,N-dimethylacetamide, N,N-dimethylformamide) and characterized by the X-ray single crystal analysis. The structures of the first three solvates is similar to each other in structures and represent a one-dimensional polymer chain, the fourth solvate has the discrete structure containing [Cd(DMF) 6] 2+ and [Cd 2I 6] 2– ions, and the fifth solvate contains discrete [Cd(DMA) 6] 2+ cations and the polymer anionic fragment [Cd 5I 12] n 2n–.
KW - DMF
KW - N,N-dimethylacetamide
KW - cadmium
KW - coordination polymers
KW - noncovalent contacts
KW - CATALYSIS
KW - COMPLEXES
KW - ZINC
UR - http://www.scopus.com/inward/record.url?scp=85042852320&partnerID=8YFLogxK
UR - http://www.mendeley.com/research/solubility-delement-salts-organic-aqueousorganic-solvents-visup1supstructure-thermal-stability-cadmi
U2 - 10.1134/S1070363218010012
DO - 10.1134/S1070363218010012
M3 - Article
VL - 88
SP - 1
EP - 6
JO - Russian Journal of General Chemistry
JF - Russian Journal of General Chemistry
SN - 1070-3632
IS - 1
ER -
ID: 17652961