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Solubility in the system acetic acid –n-amyl alcohol –n-amyl acetate –Water at 293.15 K, 303.15 K, 313.15 K and 323.15 K and atmospheric pressure. / Trofimova, Maya ; Misikov, Georgii ; Samarov, Artemiy ; Prikhodko, Igor ; Toikka, Maria .

в: Journal of Chemical Thermodynamics, Том 161, 106515, 10.2021.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{65341d704f7b45a4982cb6ceed014569,
title = "Solubility in the system acetic acid –n-amyl alcohol –n-amyl acetate –Water at 293.15 K, 303.15 K, 313.15 K and 323.15 K and atmospheric pressure",
abstract = "Solubility of the quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water was investigated at 293.15 K, 303.15 K, 313.15 K, 323.15 K and atmospheric pressure. Binodal curves and binodalsurfaces were determined using isothermal titration (cloud-point technique) and presented in composition simplices including 3D phase diagrams in composition tetrahedron. Binary mixtures were carriedout by the gas chromatography method. Experimental data were predicted using UNIFAC model, and itwas found that the calculating results of liquid–liquid equilibria (LLE) are in inconsistent agreement withthe experimental data on solubility at all temperatures.",
keywords = "Solubility, n-Amyl acetate, N-pentyl acetate, UNIFAC, N-amyl acetate, 1-PROPANOL, OXALIC-ACID, 2-METHYL-1-PROPANOL, CRITICAL STATES, PLUS 1-PENTANOL, TEMPERATURE, LIQUID-LIQUID EQUILIBRIA, ETHYL-ACETATE, AQUEOUS-PHASE DIAGRAMS, BUTYL ACETATE",
author = "Maya Trofimova and Georgii Misikov and Artemiy Samarov and Igor Prikhodko and Maria Toikka",
note = "Publisher Copyright: {\textcopyright} 2021 Elsevier Ltd",
year = "2021",
month = oct,
doi = "10.1016/j.jct.2021.106515",
language = "English",
volume = "161",
journal = "Journal of Chemical Thermodynamics",
issn = "0021-9614",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Solubility in the system acetic acid –n-amyl alcohol –n-amyl acetate –Water at 293.15 K, 303.15 K, 313.15 K and 323.15 K and atmospheric pressure

AU - Trofimova, Maya

AU - Misikov, Georgii

AU - Samarov, Artemiy

AU - Prikhodko, Igor

AU - Toikka, Maria

N1 - Publisher Copyright: © 2021 Elsevier Ltd

PY - 2021/10

Y1 - 2021/10

N2 - Solubility of the quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water was investigated at 293.15 K, 303.15 K, 313.15 K, 323.15 K and atmospheric pressure. Binodal curves and binodalsurfaces were determined using isothermal titration (cloud-point technique) and presented in composition simplices including 3D phase diagrams in composition tetrahedron. Binary mixtures were carriedout by the gas chromatography method. Experimental data were predicted using UNIFAC model, and itwas found that the calculating results of liquid–liquid equilibria (LLE) are in inconsistent agreement withthe experimental data on solubility at all temperatures.

AB - Solubility of the quaternary system acetic acid – n-amyl alcohol – n-amyl acetate – water was investigated at 293.15 K, 303.15 K, 313.15 K, 323.15 K and atmospheric pressure. Binodal curves and binodalsurfaces were determined using isothermal titration (cloud-point technique) and presented in composition simplices including 3D phase diagrams in composition tetrahedron. Binary mixtures were carriedout by the gas chromatography method. Experimental data were predicted using UNIFAC model, and itwas found that the calculating results of liquid–liquid equilibria (LLE) are in inconsistent agreement withthe experimental data on solubility at all temperatures.

KW - Solubility

KW - n-Amyl acetate

KW - N-pentyl acetate

KW - UNIFAC

KW - N-amyl acetate

KW - 1-PROPANOL

KW - OXALIC-ACID

KW - 2-METHYL-1-PROPANOL

KW - CRITICAL STATES

KW - PLUS 1-PENTANOL

KW - TEMPERATURE

KW - LIQUID-LIQUID EQUILIBRIA

KW - ETHYL-ACETATE

KW - AQUEOUS-PHASE DIAGRAMS

KW - BUTYL ACETATE

UR - http://www.scopus.com/inward/record.url?scp=85106575490&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/d8ef4e0a-b6b7-333d-bc6b-c95183b60430/

U2 - 10.1016/j.jct.2021.106515

DO - 10.1016/j.jct.2021.106515

M3 - Article

VL - 161

JO - Journal of Chemical Thermodynamics

JF - Journal of Chemical Thermodynamics

SN - 0021-9614

M1 - 106515

ER -

ID: 77932321