Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Solid Phases in the System L‑Valine - L‑Isoleucine. / Isakov, Anton I.; Kotelnikova, Elena N.; Muenzberg, Stephan; Bocharov, Sergey N.; Lorenz, Heike.
в: Crystal Growth and Design, Том 16, № 5, 2016, стр. 2653–2661.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Solid Phases in the System L‑Valine - L‑Isoleucine
AU - Isakov, Anton I.
AU - Kotelnikova, Elena N.
AU - Muenzberg, Stephan
AU - Bocharov, Sergey N.
AU - Lorenz, Heike
PY - 2016
Y1 - 2016
N2 - Samples crystallized in the system l-Val—l-Ile—water by cooling and isothermal methods were studied. The ternary solubility diagram of the system was established based on liquid chromatography data. A non-equimolar 2:1 discrete compound V2I was discovered, and its crystal structure was determined via single crystal diffractometry. Narrow regions of solid solutions close to the discrete phases and two wide two-phase areas were distinguished by X-ray diffractometry analyses.
AB - Samples crystallized in the system l-Val—l-Ile—water by cooling and isothermal methods were studied. The ternary solubility diagram of the system was established based on liquid chromatography data. A non-equimolar 2:1 discrete compound V2I was discovered, and its crystal structure was determined via single crystal diffractometry. Narrow regions of solid solutions close to the discrete phases and two wide two-phase areas were distinguished by X-ray diffractometry analyses.
KW - valine
KW - isoleucine
KW - amino acids
KW - non-equimolar compounds
KW - discrete compounds
KW - enantiomers
KW - solid solutions
KW - solubility
KW - chromatography
KW - X-ray diffractometry
U2 - 10.1021/acs.cgd.5b01766
DO - 10.1021/acs.cgd.5b01766
M3 - Article
VL - 16
SP - 2653
EP - 2661
JO - Crystal Growth and Design
JF - Crystal Growth and Design
SN - 1528-7483
IS - 5
ER -
ID: 7565310