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Soft X-ray Li-K and Si-L 2,3 emission from crystalline and amorphous lithium silicides in lithium-ion batteries anode. / Lyalin, Andrey; Kuznetsov, Vladimir G.; Nakayama, Akira; Abarenkov, Igor V.; Tupitsyn, Ilya I.; Gabis, Igor E.; Uosaki, Kohei; Taketsugu, Tetsuya.

в: Journal of the Electrochemical Society, Том 166, № 3, 19.01.2019, стр. A5362-A5368.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Lyalin, A, Kuznetsov, VG, Nakayama, A, Abarenkov, IV, Tupitsyn, II, Gabis, IE, Uosaki, K & Taketsugu, T 2019, 'Soft X-ray Li-K and Si-L 2,3 emission from crystalline and amorphous lithium silicides in lithium-ion batteries anode', Journal of the Electrochemical Society, Том. 166, № 3, стр. A5362-A5368. https://doi.org/10.1149/2.0551903jes

APA

Lyalin, A., Kuznetsov, V. G., Nakayama, A., Abarenkov, I. V., Tupitsyn, I. I., Gabis, I. E., Uosaki, K., & Taketsugu, T. (2019). Soft X-ray Li-K and Si-L 2,3 emission from crystalline and amorphous lithium silicides in lithium-ion batteries anode. Journal of the Electrochemical Society, 166(3), A5362-A5368. https://doi.org/10.1149/2.0551903jes

Vancouver

Author

Lyalin, Andrey ; Kuznetsov, Vladimir G. ; Nakayama, Akira ; Abarenkov, Igor V. ; Tupitsyn, Ilya I. ; Gabis, Igor E. ; Uosaki, Kohei ; Taketsugu, Tetsuya. / Soft X-ray Li-K and Si-L 2,3 emission from crystalline and amorphous lithium silicides in lithium-ion batteries anode. в: Journal of the Electrochemical Society. 2019 ; Том 166, № 3. стр. A5362-A5368.

BibTeX

@article{eff1ade4b9874f159175b0d7d8ce9c21,
title = "Soft X-ray Li-K and Si-L 2,3 emission from crystalline and amorphous lithium silicides in lithium-ion batteries anode",
abstract = " Soft X-ray Li-K and Si-L 2,3 emission spectra of crystalline and amorphous lithium silicides Li 13 Si 4 and Li 15 Si 4 forming upon electrochemical lithiation of silicon anode in lithium-ion batteries (LIBs) have been investigated theoretically. It is shown that shape and energy position of X-ray emission bands can be used for determination of the chemical structure and composition of the electrochemically lithiated silicon, while the intensities of Li-K and Si-L 2,3 bands provide information on Li concentration. It is demonstrated that theoretical methods of soft X-ray emission spectroscopy (XES) can be used as a powerful tool for the detailed analysis of the electronic and structural properties of Li-Si alloys in LIBs. ",
keywords = "ELECTROCHEMICAL LITHIATION, 1ST PRINCIPLES, SILICON ELECTRODES, PSEUDOPOTENTIALS, NANOWIRES, EVOLUTION, DIFFUSION, INSERTION, KINETICS",
author = "Andrey Lyalin and Kuznetsov, {Vladimir G.} and Akira Nakayama and Abarenkov, {Igor V.} and Tupitsyn, {Ilya I.} and Gabis, {Igor E.} and Kohei Uosaki and Tetsuya Taketsugu",
year = "2019",
month = jan,
day = "19",
doi = "10.1149/2.0551903jes",
language = "English",
volume = "166",
pages = "A5362--A5368",
journal = "Journal of the Electrochemical Society",
issn = "0013-4651",
publisher = "The Electrochemical Society",
number = "3",

}

RIS

TY - JOUR

T1 - Soft X-ray Li-K and Si-L 2,3 emission from crystalline and amorphous lithium silicides in lithium-ion batteries anode

AU - Lyalin, Andrey

AU - Kuznetsov, Vladimir G.

AU - Nakayama, Akira

AU - Abarenkov, Igor V.

AU - Tupitsyn, Ilya I.

AU - Gabis, Igor E.

AU - Uosaki, Kohei

AU - Taketsugu, Tetsuya

PY - 2019/1/19

Y1 - 2019/1/19

N2 - Soft X-ray Li-K and Si-L 2,3 emission spectra of crystalline and amorphous lithium silicides Li 13 Si 4 and Li 15 Si 4 forming upon electrochemical lithiation of silicon anode in lithium-ion batteries (LIBs) have been investigated theoretically. It is shown that shape and energy position of X-ray emission bands can be used for determination of the chemical structure and composition of the electrochemically lithiated silicon, while the intensities of Li-K and Si-L 2,3 bands provide information on Li concentration. It is demonstrated that theoretical methods of soft X-ray emission spectroscopy (XES) can be used as a powerful tool for the detailed analysis of the electronic and structural properties of Li-Si alloys in LIBs.

AB - Soft X-ray Li-K and Si-L 2,3 emission spectra of crystalline and amorphous lithium silicides Li 13 Si 4 and Li 15 Si 4 forming upon electrochemical lithiation of silicon anode in lithium-ion batteries (LIBs) have been investigated theoretically. It is shown that shape and energy position of X-ray emission bands can be used for determination of the chemical structure and composition of the electrochemically lithiated silicon, while the intensities of Li-K and Si-L 2,3 bands provide information on Li concentration. It is demonstrated that theoretical methods of soft X-ray emission spectroscopy (XES) can be used as a powerful tool for the detailed analysis of the electronic and structural properties of Li-Si alloys in LIBs.

KW - ELECTROCHEMICAL LITHIATION

KW - 1ST PRINCIPLES

KW - SILICON ELECTRODES

KW - PSEUDOPOTENTIALS

KW - NANOWIRES

KW - EVOLUTION

KW - DIFFUSION

KW - INSERTION

KW - KINETICS

UR - http://www.scopus.com/inward/record.url?scp=85063087585&partnerID=8YFLogxK

U2 - 10.1149/2.0551903jes

DO - 10.1149/2.0551903jes

M3 - Article

AN - SCOPUS:85063087585

VL - 166

SP - A5362-A5368

JO - Journal of the Electrochemical Society

JF - Journal of the Electrochemical Society

SN - 0013-4651

IS - 3

ER -

ID: 42177923