Smart materials as modifiers of capillary electromigration methods in bioanalysis

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Smart materials as modifiers of capillary electromigration methods in bioanalysis. / Kartsova, L.; Maliushevska, A.; Adamova, A.; Ganieva, A.

в: TrAC - Trends in Analytical Chemistry, Том 191, 09.06.2025.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{b7cbe4b8639f4b05ba4e7890f397079d,

title = "Smart materials as modifiers of capillary electromigration methods in bioanalysis",

abstract = "Smart materials-based polyfunctional capillary coatings used as stationary or pseudostationary phases significantly increase the capabilities of the capillary electromigration methods and provide separation, analysis, and on-line concentration of ionic, hydrophilic, hydrophobic, and neutral analytes in one analytical cycle while implementing different separation mechanisms of the individual capillary electromigration methods. The review covers such topics as the use of micellar polymers, ionic liquids, oligosaccharides, metal-organic and covalent organic frameworks, molecularly imprinted polymers, nanoparticles, and other smart materials for the synthesis of capillary electrochromatography stationary phases and summarizes and comprehends existing approaches to the development of smart materials for electromigration techniques. The unique properties of smart materials are discussed in terms of implementing various modes of hydrophilic capillary electrochromatography and micellar electrokinetic chromatography, which significantly expands method's analytical limits. Particular attention is paid to the synergistic effect exhibited by the joint use of two or more smart materials in electrophoretic analysis. A special section is devoted to chiral electrophoretic and electrochromatographic separations in bioanalysis involving smart materials. {\textcopyright} 2025 Elsevier B.V., All rights reserved.",

keywords = "Biologically active substances, Capillary electrochromatography, Capillary electrophoresis, Enantioseparations, Smart materials, Bioactivity, Crystalline materials, Electrochromism, Electromigration, Hydrophilicity, Intelligent materials, Ionic liquids, Liquid chromatography, Bioanalysis, Capillary coatings, Capillary electromigration methods, Material-based, Polyfunctional, Polyfunctionals, Stationary phase, ionic liquid, molecularly imprinted polymer, nanoparticle, oligosaccharide, polymer, smart material, capillary, capillary electrochromatography, capillary electrophoresis, electrophoresis, enantioseparation, ionization, micellar electrokinetic chromatography, review, synthesis",

author = "L. Kartsova and A. Maliushevska and A. Adamova and A. Ganieva",

note = "Export Date: 01 November 2025; Cited By: 0; Correspondence Address: A. Maliushevska; St. Petersburg State University, St. Petersburg, Petrodvorets, 198504, Russian Federation; email: malushevskaa@gmail.com; CODEN: TTAED",

year = "2025",

month = jun,

day = "9",

doi = "10.1016/j.trac.2025.118335",

language = "Английский",

volume = "191",

journal = "TrAC - Trends in Analytical Chemistry",

issn = "0165-9936",

publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Smart materials as modifiers of capillary electromigration methods in bioanalysis

AU - Kartsova, L.

AU - Maliushevska, A.

AU - Adamova, A.

AU - Ganieva, A.

N1 - Export Date: 01 November 2025; Cited By: 0; Correspondence Address: A. Maliushevska; St. Petersburg State University, St. Petersburg, Petrodvorets, 198504, Russian Federation; email: malushevskaa@gmail.com; CODEN: TTAED

PY - 2025/6/9

Y1 - 2025/6/9

N2 - Smart materials-based polyfunctional capillary coatings used as stationary or pseudostationary phases significantly increase the capabilities of the capillary electromigration methods and provide separation, analysis, and on-line concentration of ionic, hydrophilic, hydrophobic, and neutral analytes in one analytical cycle while implementing different separation mechanisms of the individual capillary electromigration methods. The review covers such topics as the use of micellar polymers, ionic liquids, oligosaccharides, metal-organic and covalent organic frameworks, molecularly imprinted polymers, nanoparticles, and other smart materials for the synthesis of capillary electrochromatography stationary phases and summarizes and comprehends existing approaches to the development of smart materials for electromigration techniques. The unique properties of smart materials are discussed in terms of implementing various modes of hydrophilic capillary electrochromatography and micellar electrokinetic chromatography, which significantly expands method's analytical limits. Particular attention is paid to the synergistic effect exhibited by the joint use of two or more smart materials in electrophoretic analysis. A special section is devoted to chiral electrophoretic and electrochromatographic separations in bioanalysis involving smart materials. © 2025 Elsevier B.V., All rights reserved.

AB - Smart materials-based polyfunctional capillary coatings used as stationary or pseudostationary phases significantly increase the capabilities of the capillary electromigration methods and provide separation, analysis, and on-line concentration of ionic, hydrophilic, hydrophobic, and neutral analytes in one analytical cycle while implementing different separation mechanisms of the individual capillary electromigration methods. The review covers such topics as the use of micellar polymers, ionic liquids, oligosaccharides, metal-organic and covalent organic frameworks, molecularly imprinted polymers, nanoparticles, and other smart materials for the synthesis of capillary electrochromatography stationary phases and summarizes and comprehends existing approaches to the development of smart materials for electromigration techniques. The unique properties of smart materials are discussed in terms of implementing various modes of hydrophilic capillary electrochromatography and micellar electrokinetic chromatography, which significantly expands method's analytical limits. Particular attention is paid to the synergistic effect exhibited by the joint use of two or more smart materials in electrophoretic analysis. A special section is devoted to chiral electrophoretic and electrochromatographic separations in bioanalysis involving smart materials. © 2025 Elsevier B.V., All rights reserved.

KW - Biologically active substances

KW - Capillary electrochromatography

KW - Capillary electrophoresis

KW - Enantioseparations

KW - Smart materials

KW - Bioactivity

KW - Crystalline materials

KW - Electrochromism

KW - Electromigration

KW - Hydrophilicity

KW - Intelligent materials

KW - Ionic liquids

KW - Liquid chromatography

KW - Bioanalysis

KW - Capillary coatings

KW - Capillary electromigration methods

KW - Material-based

KW - Polyfunctional

KW - Polyfunctionals

KW - Stationary phase

KW - ionic liquid

KW - molecularly imprinted polymer

KW - nanoparticle

KW - oligosaccharide

KW - polymer

KW - smart material

KW - capillary

KW - capillary electrochromatography

KW - capillary electrophoresis

KW - electrophoresis

KW - enantioseparation

KW - ionization

KW - micellar electrokinetic chromatography

KW - review

KW - synthesis

UR - https://www.mendeley.com/catalogue/f457f02c-c0ff-3a0c-bf2f-d04c0840e6ea/

U2 - 10.1016/j.trac.2025.118335

DO - 10.1016/j.trac.2025.118335

M3 - статья

VL - 191

JO - TrAC - Trends in Analytical Chemistry

JF - TrAC - Trends in Analytical Chemistry

SN - 0165-9936

ER -

ID: 143729121

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