TY - JOUR

T1 - Simultaneous quantification of Zr, Mo, U, Np and Pu in technological solutions of spent nuclear fuel reprocessing with a potentiometric multisensor system

AU - Savosina, J.

AU - Agafonova-Moroz, M.

AU - Naumov, A.

AU - Nikolaev, A.

AU - Lumpov, A.

AU - Babain, V.

AU - Legin, A.

AU - Olivieri, A.

AU - Parastar, H.

AU - Kirsanov, D.

N1 - Цитирования:2 Export Date: 28 November 2023 CODEN: SABCE Адрес для корреспонденции: Kirsanov, D.; Institute of Chemistry, Universitetsky Prospect, 26, Russian Federation; эл. почта: d.kirsanov@gmail.com Пристатейные ссылки: Herbst, R.S., Baron, P., Nilsson, M., Standard and advanced separation: PUREX processes for nuclear fuel reprocessing (2011), pp. 141-175. , https://doi.org/10.1533/9780857092274.2.141, Adv. Sep. Tech. Nucl. Fuel Reprocess. Radioact. Waste Treat., Elsevier; Wanna, N.N., Dobney, A., Van Hoecke, K., Vasile, M., Vanhaecke, F., Quantification of uranium, plutonium, neodymium and gadolinium for the characterization of spent nuclear fuel using isotope dilution HPIC-SF-ICP-MS (2021) Talanta, 221; Zhu, L., Hou, X., Qiao, J., Determination of 135Cs concentration and 135Cs/137Cs ratio in waste samples from nuclear decommissioning by chemical separation and ICP-MS/MS (2021) Talanta, 221; Bryan, S.A., Levitskaia, T.G., Casella, A.J., Peterson, J.M., Johnsen, A.M., Lines, A.M., Thomas, E.M., Spectroscopic on-line monitoring for process control and safeguarding of radiochemical streams in nuclear fuel reprocessing facilities (2011), pp. 95-119. , https://doi.org/10.1533/9780857092274.1.95, Adv. Sep. Tech. Nucl. Fuel Reprocess. Radioact. 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PY - 2023/4/1

Y1 - 2023/4/1

N2 - The chemical analysis of spent nuclear fuel (SNF) reprocessing is a very challenging research field due to the high radioactivity of process streams and their complex composition. The process managing requires thorough chemical analysis to ensure safe and efficient performance. Traditional ways of chemical control of SNF reprocessing are based on sampling methods and involve long and tedious procedures, failing to provide immediate information on the process status. Recent literature suggests that potentiometric multisensor systems can be employed for on-line control. However, up to now these systems were only studied in very simple model media. This work reports on the potentiometric multisensor array applied for the first time for the simultaneous quantification of the content of actinides (uranium, plutonium, neptunium) and several other analytes (zirconium, molybdenum and nitric acid) in the complex samples obtained from the pilot extraction unit for SNF reprocessing. The same samples were also analyzed by UV-Vis spectrometry (another prospective method for on-line control) and the analytical performance of these two methods was compared using established analytical figures of merit (sensitivity and analytical sensitivity metrics) for multivariate calibration. In spite of the extremely challenging analytical task, both simple methods provide the characteristics suitable for real industrial applications. © 2023 Elsevier B.V.

AB - The chemical analysis of spent nuclear fuel (SNF) reprocessing is a very challenging research field due to the high radioactivity of process streams and their complex composition. The process managing requires thorough chemical analysis to ensure safe and efficient performance. Traditional ways of chemical control of SNF reprocessing are based on sampling methods and involve long and tedious procedures, failing to provide immediate information on the process status. Recent literature suggests that potentiometric multisensor systems can be employed for on-line control. However, up to now these systems were only studied in very simple model media. This work reports on the potentiometric multisensor array applied for the first time for the simultaneous quantification of the content of actinides (uranium, plutonium, neptunium) and several other analytes (zirconium, molybdenum and nitric acid) in the complex samples obtained from the pilot extraction unit for SNF reprocessing. The same samples were also analyzed by UV-Vis spectrometry (another prospective method for on-line control) and the analytical performance of these two methods was compared using established analytical figures of merit (sensitivity and analytical sensitivity metrics) for multivariate calibration. In spite of the extremely challenging analytical task, both simple methods provide the characteristics suitable for real industrial applications. © 2023 Elsevier B.V.

KW - Actinides

KW - Optical spectrometry

KW - Potentiometric sensor array

KW - Process analysis

KW - Spent nuclear fuel

KW - Nuclear fuel reprocessing

KW - Sensor data fusion

KW - Spectrometry

KW - On-line controls

KW - Potentiometric sensor arrays

KW - Potentiometrics

KW - Process streams

KW - Research fields

KW - Spent nuclear fuel reprocessing

KW - Spent nuclear fuels

KW - Technological solution

KW - Potentiometers (electric measuring instruments)

UR - https://www.mendeley.com/catalogue/4ebf587b-6b59-3d7a-b32f-213320cbabcc/

U2 - 10.1016/j.snb.2023.133315

DO - 10.1016/j.snb.2023.133315

M3 - Article

VL - 380

JO - Sensors and Actuators, B: Chemical

JF - Sensors and Actuators, B: Chemical

SN - 0925-4005

M1 - 133315

ER -