Результаты исследований: Научные публикации в периодических изданиях › статья в журнале по материалам конференции › Рецензирование
Simulations of CO2 multi-temperature vibrational kinetics on the basis of new relaxation time models. / Косарева, Алёна Александровна; Кустова, Елена Владимировна; Мехоношина, Мария Андреевна.
в: Journal of Physics: Conference Series, Том 1959, № 1, 012030, 14.07.2021.Результаты исследований: Научные публикации в периодических изданиях › статья в журнале по материалам конференции › Рецензирование
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TY - JOUR
T1 - Simulations of CO2 multi-temperature vibrational kinetics on the basis of new relaxation time models
AU - Косарева, Алёна Александровна
AU - Кустова, Елена Владимировна
AU - Мехоношина, Мария Андреевна
N1 - Conference code: IX
PY - 2021/7/14
Y1 - 2021/7/14
N2 - Vibrational relaxation of a single-component carbon dioxide in adiabatic thermal bath is studied in multi-temperature approaches using several models for the vibrational relaxation time. The energy production terms in two- A nd three-temperature vibrational energy relaxation equations are written in the frame of the common Landau-Teller model as well using corrections based on introducing multi-temperature relaxation times for various vibrational energy exchanges within and between CO2 modes. For the relaxation time evaluation, two theoretical models for the transition probabilities are implemented: The first-order perturbation theory and the forced harmonic oscillator model; several experimental data sets are also assessed. It is shown that the forced harmonic oscillator model provides satisfactory agreement with experimental relaxation times in a wide temperature range. Solutions obtained using the two theoretical models for the transition probabilities show essentially different trends, incubation time and relaxation rate.
AB - Vibrational relaxation of a single-component carbon dioxide in adiabatic thermal bath is studied in multi-temperature approaches using several models for the vibrational relaxation time. The energy production terms in two- A nd three-temperature vibrational energy relaxation equations are written in the frame of the common Landau-Teller model as well using corrections based on introducing multi-temperature relaxation times for various vibrational energy exchanges within and between CO2 modes. For the relaxation time evaluation, two theoretical models for the transition probabilities are implemented: The first-order perturbation theory and the forced harmonic oscillator model; several experimental data sets are also assessed. It is shown that the forced harmonic oscillator model provides satisfactory agreement with experimental relaxation times in a wide temperature range. Solutions obtained using the two theoretical models for the transition probabilities show essentially different trends, incubation time and relaxation rate.
UR - http://www.scopus.com/inward/record.url?scp=85111986095&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/6435a9c4-bd79-3944-9101-d653817169d0/
U2 - doi:10.1088/1742-6596/1959/1/012030
DO - doi:10.1088/1742-6596/1959/1/012030
M3 - Conference article
VL - 1959
JO - Journal of Physics: Conference Series
JF - Journal of Physics: Conference Series
SN - 1742-6588
IS - 1
M1 - 012030
Y2 - 9 March 2021 through 12 March 2021
ER -
ID: 78890045