Sign of the spin-polarized effects in the chemical shifts of the X-ray Cu Kα1,2 emission transitions

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Sign of the spin-polarized effects in the chemical shifts of the X-ray Cu Kα_1,2 emission transitions. / Tupitsyn, I. I.; Makarov, L. L.; Batrakov, J. F.

в: Journal of Physics and Chemistry of Solids, Том 59, № 5, 05.1998, стр. 809-817.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Author

Tupitsyn, I. I. ; Makarov, L. L. ; Batrakov, J. F. / Sign of the spin-polarized effects in the chemical shifts of the X-ray Cu Kα_1,2 emission transitions. в: Journal of Physics and Chemistry of Solids. 1998 ; Том 59, № 5. стр. 809-817.

BibTeX

@article{0d735c0014c2477a98ee118227461047,

title = "Sign of the spin-polarized effects in the chemical shifts of the X-ray Cu Kα1,2 emission transitions",

abstract = "A theoretical treatment of X-ray chemical shift (Ch.S.) was proposed taking into account different contributions to it. This theoretical approach was applied to analyse the effects following the formation of solid solutions of Cu2+ in host lattices of the highly symmetrical oxides NiO and MgO. The interpretation of the X-ray effects is based on the correlation observed between the Ch.S. and magnetic data and on the results of the present theoretical work. The most important result is the conclusion that the innermost Kα X-ray transitions of a magnetic atom follow a mostly parallel orientation of the spins of uncoupled valent electrons and the inner electron holes involved into X-ray transition.",

keywords = "Magnetic moment, Relaxation, Spin, X-ray chemical shift",

author = "Tupitsyn, {I. I.} and Makarov, {L. L.} and Batrakov, {J. F.}",

year = "1998",

month = may,

doi = "10.1016/S0022-3697(97)00030-9",

language = "English",

volume = "59",

pages = "809--817",

journal = "Journal of Physics and Chemistry of Solids",

issn = "0022-3697",

publisher = "Elsevier",

number = "5",

}

RIS

TY - JOUR

T1 - Sign of the spin-polarized effects in the chemical shifts of the X-ray Cu Kα1,2 emission transitions

AU - Tupitsyn, I. I.

AU - Makarov, L. L.

AU - Batrakov, J. F.

PY - 1998/5

Y1 - 1998/5

N2 - A theoretical treatment of X-ray chemical shift (Ch.S.) was proposed taking into account different contributions to it. This theoretical approach was applied to analyse the effects following the formation of solid solutions of Cu2+ in host lattices of the highly symmetrical oxides NiO and MgO. The interpretation of the X-ray effects is based on the correlation observed between the Ch.S. and magnetic data and on the results of the present theoretical work. The most important result is the conclusion that the innermost Kα X-ray transitions of a magnetic atom follow a mostly parallel orientation of the spins of uncoupled valent electrons and the inner electron holes involved into X-ray transition.

AB - A theoretical treatment of X-ray chemical shift (Ch.S.) was proposed taking into account different contributions to it. This theoretical approach was applied to analyse the effects following the formation of solid solutions of Cu2+ in host lattices of the highly symmetrical oxides NiO and MgO. The interpretation of the X-ray effects is based on the correlation observed between the Ch.S. and magnetic data and on the results of the present theoretical work. The most important result is the conclusion that the innermost Kα X-ray transitions of a magnetic atom follow a mostly parallel orientation of the spins of uncoupled valent electrons and the inner electron holes involved into X-ray transition.

KW - Magnetic moment

KW - Relaxation

KW - Spin

KW - X-ray chemical shift

UR - http://www.scopus.com/inward/record.url?scp=0032066593&partnerID=8YFLogxK

U2 - 10.1016/S0022-3697(97)00030-9

DO - 10.1016/S0022-3697(97)00030-9

M3 - Article

AN - SCOPUS:0032066593

VL - 59

SP - 809

EP - 817

JO - Journal of Physics and Chemistry of Solids

JF - Journal of Physics and Chemistry of Solids

SN - 0022-3697

IS - 5

ER -

ID: 49763623