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Separation of Rare Earth and Transplutonium Elements in Carbonate Media. / Баланцев, Игорь Владимирович; Караван, Мария Дмитриевна; Смирнов, Игорь Валентинович.

в: Radiochemistry, Том 65, № 2, 01.04.2023, стр. 230-233.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{7b8d4f48bfea41a79a2affa0bdc22aa1,
title = "Separation of Rare Earth and Transplutonium Elements in Carbonate Media",
abstract = "Abstract: The extraction ability and selectivity of nonmacrocyclic (8-quinolinol and 2,3-dihydroxynaphthelene) and macrocyclic (sulfur-containing calixarene derivatives) ligands toward rare earth and transplutonium elements in carbonate media was studied. Both macrocyclic and nonmacrocyclic derivatives showed moderate selectivity to americium in the Am/Eu pair (separation factor SF from 1.6 to 14 at pH > 12), and sulfur-containing calixarenes showed also high selectivity to Am in the Am/Cm pair (SF 3–8 at pH > 13). The compounds studied show promise as extractants for group recovery and separation of actinides, and also for separation of rare earth and transplutonium elements in carbonate media.",
keywords = "americium, curium, europium, extraction, macrocyclic ligands, nonmacrocyclic ligands, separation",
author = "Баланцев, {Игорь Владимирович} and Караван, {Мария Дмитриевна} and Смирнов, {Игорь Валентинович}",
year = "2023",
month = apr,
day = "1",
doi = "10.1134/s106636222302011x",
language = "English",
volume = "65",
pages = "230--233",
journal = "Radiochemistry",
issn = "1066-3622",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - Separation of Rare Earth and Transplutonium Elements in Carbonate Media

AU - Баланцев, Игорь Владимирович

AU - Караван, Мария Дмитриевна

AU - Смирнов, Игорь Валентинович

PY - 2023/4/1

Y1 - 2023/4/1

N2 - Abstract: The extraction ability and selectivity of nonmacrocyclic (8-quinolinol and 2,3-dihydroxynaphthelene) and macrocyclic (sulfur-containing calixarene derivatives) ligands toward rare earth and transplutonium elements in carbonate media was studied. Both macrocyclic and nonmacrocyclic derivatives showed moderate selectivity to americium in the Am/Eu pair (separation factor SF from 1.6 to 14 at pH > 12), and sulfur-containing calixarenes showed also high selectivity to Am in the Am/Cm pair (SF 3–8 at pH > 13). The compounds studied show promise as extractants for group recovery and separation of actinides, and also for separation of rare earth and transplutonium elements in carbonate media.

AB - Abstract: The extraction ability and selectivity of nonmacrocyclic (8-quinolinol and 2,3-dihydroxynaphthelene) and macrocyclic (sulfur-containing calixarene derivatives) ligands toward rare earth and transplutonium elements in carbonate media was studied. Both macrocyclic and nonmacrocyclic derivatives showed moderate selectivity to americium in the Am/Eu pair (separation factor SF from 1.6 to 14 at pH > 12), and sulfur-containing calixarenes showed also high selectivity to Am in the Am/Cm pair (SF 3–8 at pH > 13). The compounds studied show promise as extractants for group recovery and separation of actinides, and also for separation of rare earth and transplutonium elements in carbonate media.

KW - americium

KW - curium

KW - europium

KW - extraction

KW - macrocyclic ligands

KW - nonmacrocyclic ligands

KW - separation

UR - https://www.mendeley.com/catalogue/57797ed0-2f05-378b-bdb0-7a91baf63685/

U2 - 10.1134/s106636222302011x

DO - 10.1134/s106636222302011x

M3 - Article

VL - 65

SP - 230

EP - 233

JO - Radiochemistry

JF - Radiochemistry

SN - 1066-3622

IS - 2

ER -

ID: 114020012