Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Self-assembly in aqueous solutions of imidazolium ionic liquids and their mixtures with an anionic surfactant. / Smirnova, Natalia A.; Vanin, Alexandr A.; Safonova, Evgenia A.; Pukinsky, Igor B.; Anufrikov, Yuri A.; Makarov, Alexey L.
в: Journal of Colloid and Interface Science, Том 336, № 2, 15.08.2009, стр. 793-802.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Self-assembly in aqueous solutions of imidazolium ionic liquids and their mixtures with an anionic surfactant
AU - Smirnova, Natalia A.
AU - Vanin, Alexandr A.
AU - Safonova, Evgenia A.
AU - Pukinsky, Igor B.
AU - Anufrikov, Yuri A.
AU - Makarov, Alexey L.
PY - 2009/8/15
Y1 - 2009/8/15
N2 - Experimental data on micellization in aqueous solutions of 1-alkyl-3-methylimidazolium salts [Cnmim]X and their mixtures with sodium dodecyl sulfate (NaDS) are reviewed. New results (the critical micelle concentration and enthalpy of micellization) are presented for mixtures of [C4mim]PF6, [C6mim]BF4, [C6mim]Br and [C10mim]Br with NaDS. Our data cover a wide range (from 0 to 0.9) of solvent-free based mole fractions of ionic liquid (IL). Even very small addition of ILs substantially decreases the cmc of NaDS due to the combined effect of electrostatic and hydrophobic interactions, and formation of mixed micelles. It is shown that the quasichemical aggregation model by Nagarajan and Ruckenstein may be successfully applied to aqueous solutions of long-chain ILs and their mixtures with NaDS. The local structure of micelles is obtained from all-atom MD simulations for [Cnmim]Br and [Cnmim]X + NaDS in aqueous medium.
AB - Experimental data on micellization in aqueous solutions of 1-alkyl-3-methylimidazolium salts [Cnmim]X and their mixtures with sodium dodecyl sulfate (NaDS) are reviewed. New results (the critical micelle concentration and enthalpy of micellization) are presented for mixtures of [C4mim]PF6, [C6mim]BF4, [C6mim]Br and [C10mim]Br with NaDS. Our data cover a wide range (from 0 to 0.9) of solvent-free based mole fractions of ionic liquid (IL). Even very small addition of ILs substantially decreases the cmc of NaDS due to the combined effect of electrostatic and hydrophobic interactions, and formation of mixed micelles. It is shown that the quasichemical aggregation model by Nagarajan and Ruckenstein may be successfully applied to aqueous solutions of long-chain ILs and their mixtures with NaDS. The local structure of micelles is obtained from all-atom MD simulations for [Cnmim]Br and [Cnmim]X + NaDS in aqueous medium.
KW - Aqueous micellar solutions
KW - Imidazolium ionic liquid + sodium dodecyl sulfate mixtures
KW - Molecular dynamic simulation
KW - Thermodynamic modeling
UR - http://www.scopus.com/inward/record.url?scp=67649265332&partnerID=8YFLogxK
U2 - 10.1016/j.jcis.2009.04.004
DO - 10.1016/j.jcis.2009.04.004
M3 - Article
AN - SCOPUS:67649265332
VL - 336
SP - 793
EP - 802
JO - Journal of Colloid and Interface Science
JF - Journal of Colloid and Interface Science
SN - 0021-9797
IS - 2
ER -
ID: 9148709