Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
The rotational viscosity coefficient [Formula Presented] of [Formula Presented]-pentyl-[Formula Presented]-cyanobiphenyl in the nematic phase is investigated by combination of existing statistical-mechanical approaches (SMAs), based on a rotational diffusion model and computer simulation technique. The SMAs rest on a model in which it is assumed that the reorientation of an individual molecule is a stochastic Brownian motion in a certain potential of mean torque. According to the SMAs, [Formula Presented] is found to be a function of temperature, density, rotational diffusion coefficient, and a number of order parameters (OPs). The diffusion coefficient and the OPs were obtained from an analysis of a trajectory generated in a molecular dynamics simulation using realistic atom-atom interactions. In addition, a set of experimentally determined diffusion coefficients and OPs was used for evaluation of [Formula Presented]. Reasonable agreement between calculated and experimental values of [Formula Presented] is obtained. It is shown that near the clearing point [Formula Presented] is proportional to [Formula Presented], where [Formula Presented] is the second-rank OP. This limiting value of [Formula Presented] is in agreement with mean-field theory.
Язык оригинала | английский |
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Страницы (с-по) | 6802-6807 |
Число страниц | 6 |
Журнал | Physical Review E - Statistical Physics, Plasmas, Fluids, and Related Interdisciplinary Topics |
Том | 59 |
Номер выпуска | 6 |
DOI | |
Состояние | Опубликовано - 1 янв 1999 |
ID: 51875342