DOI

Aromatic electrophilic substitution reactions were simulated by ab initio calculations of the intermediate complexes and transition states involving the dimeric and monomeric forms of aluminum chloride. With the monomeric form, breaking of the catalytic cycle should be expected due to formation of a stable intermediate complex. With the dimeric form, no such complex was revealed, implying a key role this form plays in the catalysis.

Язык оригиналаанглийский
Страницы (с-по)1389-1393
Число страниц5
ЖурналRussian Journal of General Chemistry
Том74
Номер выпуска9
DOI
СостояниеОпубликовано - сен 2004

    Предметные области Scopus

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ID: 17373255