Результаты исследований: Публикации в книгах, отчётах, сборниках, трудах конференций › статья в сборнике материалов конференции › Рецензирование
Resonant Four-Wave Mixing Spectra: A Fresh Look at Photodissociation Dynamics. / Kouzov, A.; Radi, P.; Maksyutenko, P.; Kozlov, D.
The 22nd International Conference on Spectral Line Shapes (Tullahoma, University of Tennessee,USA, June 1–6, 2014). 2014. стр. 28.Результаты исследований: Публикации в книгах, отчётах, сборниках, трудах конференций › статья в сборнике материалов конференции › Рецензирование
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TY - GEN
T1 - Resonant Four-Wave Mixing Spectra: A Fresh Look at Photodissociation Dynamics
AU - Kouzov, A.
AU - Radi, P.
AU - Maksyutenko, P.
AU - Kozlov, D.
PY - 2014
Y1 - 2014
N2 - The frequency- and polarization-resolved degenerate resonant four-wave mixing (DFWM) spectra of the anisotropic states of the OH radicals produced by photolysis of H 2O2 by a planepolarized laser radiation at 266 nm are reported. The signals in the A 2 Σ + -X 2 Π(0,0) vibronic band were generated at the forward-box configuration with the photodissociation beam propagating along the box axis OZ[1]. The double and triple correlations between the dipole moment m of the dissociative transition in the parent molecule, the recoil velocity vand the angular momentum j of nascent particles –the key characteristics of the reaction path –were the main objectives of the study. To incorporate these correlations into a theoretical picture and to decouple the polarization factors from the molecular properties, the line-space approach was advanced. As a result, the DFWM intensities are expressed via the polarization factors, the Doppler-broadened profiles and the Einstein B-c
AB - The frequency- and polarization-resolved degenerate resonant four-wave mixing (DFWM) spectra of the anisotropic states of the OH radicals produced by photolysis of H 2O2 by a planepolarized laser radiation at 266 nm are reported. The signals in the A 2 Σ + -X 2 Π(0,0) vibronic band were generated at the forward-box configuration with the photodissociation beam propagating along the box axis OZ[1]. The double and triple correlations between the dipole moment m of the dissociative transition in the parent molecule, the recoil velocity vand the angular momentum j of nascent particles –the key characteristics of the reaction path –were the main objectives of the study. To incorporate these correlations into a theoretical picture and to decouple the polarization factors from the molecular properties, the line-space approach was advanced. As a result, the DFWM intensities are expressed via the polarization factors, the Doppler-broadened profiles and the Einstein B-c
KW - Resonant four-wave mixing processes
KW - rotational anisotropy
KW - photolysis
U2 - 10.1088/1742-6596/548/1/012016
DO - 10.1088/1742-6596/548/1/012016
M3 - Conference contribution
SP - 28
BT - The 22nd International Conference on Spectral Line Shapes (Tullahoma, University of Tennessee,USA, June 1–6, 2014)
ER -
ID: 7032575