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Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs). / Haimerl, Maria; Schwarzmaier, C.; Riesinger, Christoph; Timoshkin, Alexey Y. ; Melaimi, Mohand; Bertrand, Guy; Scheer, M.

в: Chemistry - A European Journal, Том 29, № 34, e202300280, 02.05.2023.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Haimerl, M, Schwarzmaier, C, Riesinger, C, Timoshkin, AY, Melaimi, M, Bertrand, G & Scheer, M 2023, 'Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs)', Chemistry - A European Journal, Том. 29, № 34, e202300280. https://doi.org/10.1002/chem.202300280

APA

Haimerl, M., Schwarzmaier, C., Riesinger, C., Timoshkin, A. Y., Melaimi, M., Bertrand, G., & Scheer, M. (2023). Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs). Chemistry - A European Journal, 29(34), [e202300280]. https://doi.org/10.1002/chem.202300280

Vancouver

Haimerl M, Schwarzmaier C, Riesinger C, Timoshkin AY, Melaimi M, Bertrand G и пр. Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs). Chemistry - A European Journal. 2023 Май 2;29(34). e202300280. https://doi.org/10.1002/chem.202300280

Author

Haimerl, Maria ; Schwarzmaier, C. ; Riesinger, Christoph ; Timoshkin, Alexey Y. ; Melaimi, Mohand ; Bertrand, Guy ; Scheer, M. / Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs). в: Chemistry - A European Journal. 2023 ; Том 29, № 34.

BibTeX

@article{90cca81acdf84fd39ea88908f1c90ed7,
title = "Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs)",
abstract = "Different cyclic (alkyl)(amino)carbenes (CAACs) were reacted with yellow arsenic. Several products [(CAAC-n)2(μ,η1:1-As2)] (n=1 (1), 4 (2)), [(CAAC-2)3(μ3,η1:1:1-As4)] (3) and [(CAAC-3)4(μ4,η1:1:1:1- As8)] (6) were isolated due to the differing steric properties of CAAC-1-4. The products contain As2, As4 or As8 units and represent the first examples of CAACs-substituted products of yellow arsenic. The reactivity of As4 was compared with the reactivities of P4 and the interpnictogen compound AsP3, which led to a series of phosphorus-containing derivatives such as ([(CAAC-3)3(μ3,η1:1:1-P4)] (4) and [(CAAC-3)4(μ4,η1:1:1:1-P8)] (7)) and [(CAAC-3)3(μ3,η1:1:1-AsP3)] (5). The products were characterized by spectroscopic and crystallographic methods and DFT computations were performed to clarify their formation pathway.",
keywords = "CAAC, interpnictogen compound, polyarsenic compounds, yellow arsenic",
author = "Maria Haimerl and C. Schwarzmaier and Christoph Riesinger and Timoshkin, {Alexey Y.} and Mohand Melaimi and Guy Bertrand and M. Scheer",
year = "2023",
month = may,
day = "2",
doi = "10.1002/chem.202300280",
language = "English",
volume = "29",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-Blackwell",
number = "34",

}

RIS

TY - JOUR

T1 - Reactivity of Yellow Arsenic towards Cyclic (Alkyl)(Amino) Carbenes (CAACs)

AU - Haimerl, Maria

AU - Schwarzmaier, C.

AU - Riesinger, Christoph

AU - Timoshkin, Alexey Y.

AU - Melaimi, Mohand

AU - Bertrand, Guy

AU - Scheer, M.

PY - 2023/5/2

Y1 - 2023/5/2

N2 - Different cyclic (alkyl)(amino)carbenes (CAACs) were reacted with yellow arsenic. Several products [(CAAC-n)2(μ,η1:1-As2)] (n=1 (1), 4 (2)), [(CAAC-2)3(μ3,η1:1:1-As4)] (3) and [(CAAC-3)4(μ4,η1:1:1:1- As8)] (6) were isolated due to the differing steric properties of CAAC-1-4. The products contain As2, As4 or As8 units and represent the first examples of CAACs-substituted products of yellow arsenic. The reactivity of As4 was compared with the reactivities of P4 and the interpnictogen compound AsP3, which led to a series of phosphorus-containing derivatives such as ([(CAAC-3)3(μ3,η1:1:1-P4)] (4) and [(CAAC-3)4(μ4,η1:1:1:1-P8)] (7)) and [(CAAC-3)3(μ3,η1:1:1-AsP3)] (5). The products were characterized by spectroscopic and crystallographic methods and DFT computations were performed to clarify their formation pathway.

AB - Different cyclic (alkyl)(amino)carbenes (CAACs) were reacted with yellow arsenic. Several products [(CAAC-n)2(μ,η1:1-As2)] (n=1 (1), 4 (2)), [(CAAC-2)3(μ3,η1:1:1-As4)] (3) and [(CAAC-3)4(μ4,η1:1:1:1- As8)] (6) were isolated due to the differing steric properties of CAAC-1-4. The products contain As2, As4 or As8 units and represent the first examples of CAACs-substituted products of yellow arsenic. The reactivity of As4 was compared with the reactivities of P4 and the interpnictogen compound AsP3, which led to a series of phosphorus-containing derivatives such as ([(CAAC-3)3(μ3,η1:1:1-P4)] (4) and [(CAAC-3)4(μ4,η1:1:1:1-P8)] (7)) and [(CAAC-3)3(μ3,η1:1:1-AsP3)] (5). The products were characterized by spectroscopic and crystallographic methods and DFT computations were performed to clarify their formation pathway.

KW - CAAC

KW - interpnictogen compound

KW - polyarsenic compounds

KW - yellow arsenic

UR - https://www.mendeley.com/catalogue/89b6138c-e6cf-3d83-b443-8dcbbb89b407/

U2 - 10.1002/chem.202300280

DO - 10.1002/chem.202300280

M3 - Article

VL - 29

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

SN - 0947-6539

IS - 34

M1 - e202300280

ER -

ID: 105514863