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REACTIVITY OF CATIONIC METHYL RHODIUM(III) COMPLEXES CIS-[RH(Β-DIKET) (PPH3)2(CH3)(CH3CN)][BPH 4] TOWARD LIGANDS OF DIFFERENT CHARACTER: PYRIDINE, CARBON MONOXIDE, AND TRIPHENYLPHOSPHINE. / Shestakova, E.P.; Varshavsky, Y.S.; Nikolskii, A.B.

в: Journal of Organometallic Chemistry, № 14, 2005, стр. 3397-3404.

Результаты исследований: Научные публикации в периодических изданиях › статья

Harvard

Shestakova, EP, Varshavsky, YS & Nikolskii, AB 2005, 'REACTIVITY OF CATIONIC METHYL RHODIUM(III) COMPLEXES CIS-[RH(Β-DIKET) (PPH3)2(CH3)(CH3CN)][BPH 4] TOWARD LIGANDS OF DIFFERENT CHARACTER: PYRIDINE, CARBON MONOXIDE, AND TRIPHENYLPHOSPHINE', Journal of Organometallic Chemistry, № 14, стр. 3397-3404. <http://elibrary.ru/item.asp?id=11990332>

APA

Shestakova, E. P., Varshavsky, Y. S., & Nikolskii, A. B. (2005). REACTIVITY OF CATIONIC METHYL RHODIUM(III) COMPLEXES CIS-[RH(Β-DIKET) (PPH3)2(CH3)(CH3CN)][BPH 4] TOWARD LIGANDS OF DIFFERENT CHARACTER: PYRIDINE, CARBON MONOXIDE, AND TRIPHENYLPHOSPHINE. Journal of Organometallic Chemistry, (14), 3397-3404. http://elibrary.ru/item.asp?id=11990332

Vancouver

Shestakova EP, Varshavsky YS, Nikolskii AB. REACTIVITY OF CATIONIC METHYL RHODIUM(III) COMPLEXES CIS-[RH(Β-DIKET) (PPH3)2(CH3)(CH3CN)][BPH 4] TOWARD LIGANDS OF DIFFERENT CHARACTER: PYRIDINE, CARBON MONOXIDE, AND TRIPHENYLPHOSPHINE. Journal of Organometallic Chemistry. 2005;(14):3397-3404.

Author

Shestakova, E.P. ; Varshavsky, Y.S. ; Nikolskii, A.B. / REACTIVITY OF CATIONIC METHYL RHODIUM(III) COMPLEXES CIS-[RH(Β-DIKET) (PPH3)2(CH3)(CH3CN)][BPH 4] TOWARD LIGANDS OF DIFFERENT CHARACTER: PYRIDINE, CARBON MONOXIDE, AND TRIPHENYLPHOSPHINE. в: Journal of Organometallic Chemistry. 2005 ; № 14. стр. 3397-3404.

BibTeX

@article{61d4b87e4f054c1994654bb7c0787447,
title = "REACTIVITY OF CATIONIC METHYL RHODIUM(III) COMPLEXES CIS-[RH(Β-DIKET) (PPH3)2(CH3)(CH3CN)][BPH 4] TOWARD LIGANDS OF DIFFERENT CHARACTER: PYRIDINE, CARBON MONOXIDE, AND TRIPHENYLPHOSPHINE",
abstract = "Cationic methyl complex of rhodium(III), cis-[Rh(Acac)(PPh 3)2(CH3)(Py)][BPh4] (1) as a single isomer with Py in the trans to PPh3 position, is formed upon the reaction of cis-[Rh(Acac)(PPh3)2(CH3)(CH 3CN)][BPh4] with pyridine in methylene chloride solution.Complex 1 was characterized by elemental analysis and by 31P{1H} and 1H NMR spectra.Cationic pentacoordinate acetyl complexes, trans-[Rh(Acac)(PPh3) 2(COCH3)][BPh4] (2) and trans-[Rh(BA)(PPh 3)2(COCH3)][BPh4] (3), are prepared by action of carbon monoxide on cis-[Rh(Acac)(PPh3) 2(CH3)(CH3CN)][BPh4] and cis-[Rh(BA)(PPh3)2(CH3)(CH3CN)] [BPh4], respectively, in methylene chloride solutions.Complexes 2 and 3 were characterized by elemental analysis and by IR, 31P{ 1H}, 13C{1H} and 1H NMR. According to NMR data, 2 and 3 in solution are non-fluxional trigonal bipyramids with β-diketonate and acetyl ligands in the equatorial plane and axial phosphines.In solutions, 2 and 3 gradually isomerize into octahedral methyl carbonyl complexes trans-[Rh(Acac)(PPh3)2(CO)(CH",
author = "E.P. Shestakova and Y.S. Varshavsky and A.B. Nikolskii",
year = "2005",
language = "English",
pages = "3397--3404",
journal = "Journal of Organometallic Chemistry",
issn = "0022-328X",
publisher = "Elsevier",
number = "14",

}

RIS

TY - JOUR

T1 - REACTIVITY OF CATIONIC METHYL RHODIUM(III) COMPLEXES CIS-[RH(Β-DIKET) (PPH3)2(CH3)(CH3CN)][BPH 4] TOWARD LIGANDS OF DIFFERENT CHARACTER: PYRIDINE, CARBON MONOXIDE, AND TRIPHENYLPHOSPHINE

AU - Shestakova, E.P.

AU - Varshavsky, Y.S.

AU - Nikolskii, A.B.

PY - 2005

Y1 - 2005

N2 - Cationic methyl complex of rhodium(III), cis-[Rh(Acac)(PPh 3)2(CH3)(Py)][BPh4] (1) as a single isomer with Py in the trans to PPh3 position, is formed upon the reaction of cis-[Rh(Acac)(PPh3)2(CH3)(CH 3CN)][BPh4] with pyridine in methylene chloride solution.Complex 1 was characterized by elemental analysis and by 31P{1H} and 1H NMR spectra.Cationic pentacoordinate acetyl complexes, trans-[Rh(Acac)(PPh3) 2(COCH3)][BPh4] (2) and trans-[Rh(BA)(PPh 3)2(COCH3)][BPh4] (3), are prepared by action of carbon monoxide on cis-[Rh(Acac)(PPh3) 2(CH3)(CH3CN)][BPh4] and cis-[Rh(BA)(PPh3)2(CH3)(CH3CN)] [BPh4], respectively, in methylene chloride solutions.Complexes 2 and 3 were characterized by elemental analysis and by IR, 31P{ 1H}, 13C{1H} and 1H NMR. According to NMR data, 2 and 3 in solution are non-fluxional trigonal bipyramids with β-diketonate and acetyl ligands in the equatorial plane and axial phosphines.In solutions, 2 and 3 gradually isomerize into octahedral methyl carbonyl complexes trans-[Rh(Acac)(PPh3)2(CO)(CH

AB - Cationic methyl complex of rhodium(III), cis-[Rh(Acac)(PPh 3)2(CH3)(Py)][BPh4] (1) as a single isomer with Py in the trans to PPh3 position, is formed upon the reaction of cis-[Rh(Acac)(PPh3)2(CH3)(CH 3CN)][BPh4] with pyridine in methylene chloride solution.Complex 1 was characterized by elemental analysis and by 31P{1H} and 1H NMR spectra.Cationic pentacoordinate acetyl complexes, trans-[Rh(Acac)(PPh3) 2(COCH3)][BPh4] (2) and trans-[Rh(BA)(PPh 3)2(COCH3)][BPh4] (3), are prepared by action of carbon monoxide on cis-[Rh(Acac)(PPh3) 2(CH3)(CH3CN)][BPh4] and cis-[Rh(BA)(PPh3)2(CH3)(CH3CN)] [BPh4], respectively, in methylene chloride solutions.Complexes 2 and 3 were characterized by elemental analysis and by IR, 31P{ 1H}, 13C{1H} and 1H NMR. According to NMR data, 2 and 3 in solution are non-fluxional trigonal bipyramids with β-diketonate and acetyl ligands in the equatorial plane and axial phosphines.In solutions, 2 and 3 gradually isomerize into octahedral methyl carbonyl complexes trans-[Rh(Acac)(PPh3)2(CO)(CH

M3 - Article

SP - 3397

EP - 3404

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 14

ER -

ID: 5121479