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Reactions of dichlorocarbene with N-(2,2-diphenylvinylidene)-anilines. 1,3-Dipolar derivatives of ketenimine-ylides. / Khlebnikov, A. F.; Novikov, M. S.; Kostikov, R. R.

в: Chemistry of Heterocyclic Compounds, Том 23, № 10, 01.10.1987, стр. 1070-1076.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{47d63140d5c54f46ac4d19b7f162a89a,
title = "Reactions of dichlorocarbene with N-(2,2-diphenylvinylidene)-anilines. 1,3-Dipolar derivatives of ketenimine-ylides",
abstract = "Ketenimine-ylides Ph2C=C-N+(=CCl2)Ar, formed by the reaction of N-(2,2-diphenylvinylidene)anilines with dichlorocarbene, generated by heating sodium trichloroacetate in chloroform, undergoes [2+3]-cycloaddition with dimethylacetylenedicarboxylate, methyl methacrylate, and dimethyl fumarate to give pyrrole derivatives; in addition, pyridine derivatives are formed in the reaction with dimethyl fumarate. In the absence of a dipolar compound, ketenimines-ylides give N-aryl-N-(2,2-diphenylvinyl)amides of di- and trichloracetic acids.",
author = "Khlebnikov, {A. F.} and Novikov, {M. S.} and Kostikov, {R. R.}",
year = "1987",
month = oct,
day = "1",
doi = "10.1007/BF00476534",
language = "English",
volume = "23",
pages = "1070--1076",
journal = "Chemistry of Heterocyclic Compounds",
issn = "0009-3122",
publisher = "Springer Nature",
number = "10",

}

RIS

TY - JOUR

T1 - Reactions of dichlorocarbene with N-(2,2-diphenylvinylidene)-anilines. 1,3-Dipolar derivatives of ketenimine-ylides

AU - Khlebnikov, A. F.

AU - Novikov, M. S.

AU - Kostikov, R. R.

PY - 1987/10/1

Y1 - 1987/10/1

N2 - Ketenimine-ylides Ph2C=C-N+(=CCl2)Ar, formed by the reaction of N-(2,2-diphenylvinylidene)anilines with dichlorocarbene, generated by heating sodium trichloroacetate in chloroform, undergoes [2+3]-cycloaddition with dimethylacetylenedicarboxylate, methyl methacrylate, and dimethyl fumarate to give pyrrole derivatives; in addition, pyridine derivatives are formed in the reaction with dimethyl fumarate. In the absence of a dipolar compound, ketenimines-ylides give N-aryl-N-(2,2-diphenylvinyl)amides of di- and trichloracetic acids.

AB - Ketenimine-ylides Ph2C=C-N+(=CCl2)Ar, formed by the reaction of N-(2,2-diphenylvinylidene)anilines with dichlorocarbene, generated by heating sodium trichloroacetate in chloroform, undergoes [2+3]-cycloaddition with dimethylacetylenedicarboxylate, methyl methacrylate, and dimethyl fumarate to give pyrrole derivatives; in addition, pyridine derivatives are formed in the reaction with dimethyl fumarate. In the absence of a dipolar compound, ketenimines-ylides give N-aryl-N-(2,2-diphenylvinyl)amides of di- and trichloracetic acids.

UR - http://www.scopus.com/inward/record.url?scp=34250094785&partnerID=8YFLogxK

U2 - 10.1007/BF00476534

DO - 10.1007/BF00476534

M3 - Article

AN - SCOPUS:34250094785

VL - 23

SP - 1070

EP - 1076

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

SN - 0009-3122

IS - 10

ER -

ID: 28245519