Reactions of carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of H4Ru4(CO) 10[k2(P,S)-Ph2P(2-CH3SC 6H4)] and Rh6(CO)14[k 2(P,S)-Ph2P(2-CH3SC6H4)] clusters

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Reactions of carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of H4Ru4(CO) 10[k2(P,S)-Ph2P(2-CH3SC 6H4)] and Rh6(CO)14[k 2(P,S)-Ph2P(2-CH3SC6H4)] clusters. / Gracheva, E. V.; Krupenya, D. V.; Pilyugina, T. S.; Tunik, S. P.; Pursiainen, J.; Haukka, M.

в: Russian Journal of General Chemistry, Том 76, № 5, 01.05.2006, стр. 682-686.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

BibTeX

@article{956a3c1a87024b5fa499a81c88ce7347,

title = "Reactions of carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of H4Ru4(CO) 10[k2(P,S)-Ph2P(2-CH3SC 6H4)] and Rh6(CO)14[k 2(P,S)-Ph2P(2-CH3SC6H4)] clusters",

abstract = "Two new disubstituted derivatives of the clusters Rh6(CO) 16 and H4Ru4(CO)12 with the heterobidentate ligand [Ph2P(2-CH3SC6H 4)] were synthesized. Structures of these compounds were completely characterized both in solid phase and solution. The H4Ru 4(CO)10[k2(P,S)-Ph2P(2-CH 3SC6H4)] cluster is an example of a structure, in which a chelating coordination of a heterobidentate ligand results in the occurrence of a center of asymmetry associated with the substituted metal atom. This type of polynuclear complexes is of interest for obtaining essentially new catalysts for asymmetric synthesis on the basis of cluster compounds.",

author = "Gracheva, {E. V.} and Krupenya, {D. V.} and Pilyugina, {T. S.} and Tunik, {S. P.} and J. Pursiainen and M. Haukka",

year = "2006",

month = may,

day = "1",

doi = "10.1134/S1070363206050033",

language = "English",

volume = "76",

pages = "682--686",

journal = "Russian Journal of General Chemistry",

issn = "1070-3632",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "5",

}

RIS

TY - JOUR

T1 - Reactions of carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of H4Ru4(CO) 10[k2(P,S)-Ph2P(2-CH3SC 6H4)] and Rh6(CO)14[k 2(P,S)-Ph2P(2-CH3SC6H4)] clusters

AU - Gracheva, E. V.

AU - Krupenya, D. V.

AU - Pilyugina, T. S.

AU - Tunik, S. P.

AU - Pursiainen, J.

AU - Haukka, M.

PY - 2006/5/1

Y1 - 2006/5/1

N2 - Two new disubstituted derivatives of the clusters Rh6(CO) 16 and H4Ru4(CO)12 with the heterobidentate ligand [Ph2P(2-CH3SC6H 4)] were synthesized. Structures of these compounds were completely characterized both in solid phase and solution. The H4Ru 4(CO)10[k2(P,S)-Ph2P(2-CH 3SC6H4)] cluster is an example of a structure, in which a chelating coordination of a heterobidentate ligand results in the occurrence of a center of asymmetry associated with the substituted metal atom. This type of polynuclear complexes is of interest for obtaining essentially new catalysts for asymmetric synthesis on the basis of cluster compounds.

AB - Two new disubstituted derivatives of the clusters Rh6(CO) 16 and H4Ru4(CO)12 with the heterobidentate ligand [Ph2P(2-CH3SC6H 4)] were synthesized. Structures of these compounds were completely characterized both in solid phase and solution. The H4Ru 4(CO)10[k2(P,S)-Ph2P(2-CH 3SC6H4)] cluster is an example of a structure, in which a chelating coordination of a heterobidentate ligand results in the occurrence of a center of asymmetry associated with the substituted metal atom. This type of polynuclear complexes is of interest for obtaining essentially new catalysts for asymmetric synthesis on the basis of cluster compounds.

UR - http://www.scopus.com/inward/record.url?scp=33747812546&partnerID=8YFLogxK

U2 - 10.1134/S1070363206050033

DO - 10.1134/S1070363206050033

M3 - Article

AN - SCOPUS:33747812546

VL - 76

SP - 682

EP - 686

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 5

ER -

ID: 36016993