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Reactions of 1,5-Diaryl-3-(trifluoromethyl)pent-1-en-4-yn-3-yl Cations with Benzene in TfOH. Synthesis of CF3-“Helicopter”-Like Molecules. / Зеров, Алексей Владимирович; Старова, Галина Леонидовна; Суслонов, Виталий Валерьевич; Хорошилова, Олеся Валерьевна; Васильев, Александр Викторович.

в: Organic Letters, Том 20, № 3, 02.02.2018, стр. 784-787.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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@article{cc76281b05dc4a3799de96e88fb90e7a,
title = "Reactions of 1,5-Diaryl-3-(trifluoromethyl)pent-1-en-4-yn-3-yl Cations with Benzene in TfOH. Synthesis of CF3-“Helicopter”-Like Molecules",
abstract = "Trimethylsilyl ethers of 1,5-diaryl-3-(trifluoromethyl)pent-1-en-4-yn-3-oles in superacid CF 3SO 3H (TfOH) give rise to the corresponding intermediate CF 3-pentenynyl cations. These species react with benzene to afford conjugated CF 3-pentenynes, which undergo subsequent cyclization, first, into CF 3-cycloheptadienes and, finally, into unusual CF 3-{"}helicopter{"}-like bicyclic structures. ",
author = "Зеров, {Алексей Владимирович} and Старова, {Галина Леонидовна} and Суслонов, {Виталий Валерьевич} and Хорошилова, {Олеся Валерьевна} and Васильев, {Александр Викторович}",
year = "2018",
month = feb,
day = "2",
doi = "10.1021/acs.orglett.7b03920",
language = "English",
volume = "20",
pages = "784--787",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society",
number = "3",

}

RIS

TY - JOUR

T1 - Reactions of 1,5-Diaryl-3-(trifluoromethyl)pent-1-en-4-yn-3-yl Cations with Benzene in TfOH. Synthesis of CF3-“Helicopter”-Like Molecules

AU - Зеров, Алексей Владимирович

AU - Старова, Галина Леонидовна

AU - Суслонов, Виталий Валерьевич

AU - Хорошилова, Олеся Валерьевна

AU - Васильев, Александр Викторович

PY - 2018/2/2

Y1 - 2018/2/2

N2 - Trimethylsilyl ethers of 1,5-diaryl-3-(trifluoromethyl)pent-1-en-4-yn-3-oles in superacid CF 3SO 3H (TfOH) give rise to the corresponding intermediate CF 3-pentenynyl cations. These species react with benzene to afford conjugated CF 3-pentenynes, which undergo subsequent cyclization, first, into CF 3-cycloheptadienes and, finally, into unusual CF 3-"helicopter"-like bicyclic structures.

AB - Trimethylsilyl ethers of 1,5-diaryl-3-(trifluoromethyl)pent-1-en-4-yn-3-oles in superacid CF 3SO 3H (TfOH) give rise to the corresponding intermediate CF 3-pentenynyl cations. These species react with benzene to afford conjugated CF 3-pentenynes, which undergo subsequent cyclization, first, into CF 3-cycloheptadienes and, finally, into unusual CF 3-"helicopter"-like bicyclic structures.

UR - http://www.scopus.com/inward/record.url?scp=85041621481&partnerID=8YFLogxK

U2 - 10.1021/acs.orglett.7b03920

DO - 10.1021/acs.orglett.7b03920

M3 - Article

VL - 20

SP - 784

EP - 787

JO - Organic Letters

JF - Organic Letters

SN - 1523-7060

IS - 3

ER -

ID: 14226138