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γ-Radiolysis of functionalized calixarenes and its effect on cesium and americium extraction. / Smirnov, Igor V.; Karavan, Maria D.; Istomina, Natalya M.; Misharev, Alexander D.; Zaripov, Salavat R.; Solovieva, Svetlana E.; Antipin, Igor S.

в: Journal of Radioanalytical and Nuclear Chemistry, Том 322, № 3, 01.12.2019, стр. 1931-1939.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

Harvard

Smirnov, IV, Karavan, MD, Istomina, NM, Misharev, AD, Zaripov, SR, Solovieva, SE & Antipin, IS 2019, 'γ-Radiolysis of functionalized calixarenes and its effect on cesium and americium extraction', Journal of Radioanalytical and Nuclear Chemistry, Том. 322, № 3, стр. 1931-1939. https://doi.org/10.1007/s10967-019-06880-4

APA

Smirnov, I. V., Karavan, M. D., Istomina, N. M., Misharev, A. D., Zaripov, S. R., Solovieva, S. E., & Antipin, I. S. (2019). γ-Radiolysis of functionalized calixarenes and its effect on cesium and americium extraction. Journal of Radioanalytical and Nuclear Chemistry, 322(3), 1931-1939. https://doi.org/10.1007/s10967-019-06880-4

Vancouver

Smirnov IV, Karavan MD, Istomina NM, Misharev AD, Zaripov SR, Solovieva SE и пр. γ-Radiolysis of functionalized calixarenes and its effect on cesium and americium extraction. Journal of Radioanalytical and Nuclear Chemistry. 2019 Дек. 1;322(3):1931-1939. https://doi.org/10.1007/s10967-019-06880-4

Author

Smirnov, Igor V. ; Karavan, Maria D. ; Istomina, Natalya M. ; Misharev, Alexander D. ; Zaripov, Salavat R. ; Solovieva, Svetlana E. ; Antipin, Igor S. / γ-Radiolysis of functionalized calixarenes and its effect on cesium and americium extraction. в: Journal of Radioanalytical and Nuclear Chemistry. 2019 ; Том 322, № 3. стр. 1931-1939.

BibTeX

@article{85b1864812d94d4b9c660c568bd66815,
title = "γ-Radiolysis of functionalized calixarenes and its effect on cesium and americium extraction",
abstract = "The effect of γ-radiation on the extraction properties of two functionalized calixarenes (p-tert-butyl-thiacalix[4]arene and p-tert-butylcalix[8]arene) is studied. The most characteristic products of the irradiated extractants interaction with diluent are identified by mass spectrometry. Extraction ability of studied calixarenes towards cesium and americium before and after irradiation is evaluated. Quantitative analysis of chloride and sulfate ions after irradiation is performed to estimate the radiological degradation degree of components. Irradiation has different effect on p-tert-butyl-thiacalix[4]arene and p-tert-butylcalix[8]arene extraction ability towards americium, which may be due to the nature and extraction ability of radiolysis products, and practically does not affect cesium extraction.",
keywords = "Alkaline media, Americium-241, Cesium-137, Functionalized calixarenes, Radioactive waste, Solvent extraction, γ-Radiolysis",
author = "Smirnov, {Igor V.} and Karavan, {Maria D.} and Istomina, {Natalya M.} and Misharev, {Alexander D.} and Zaripov, {Salavat R.} and Solovieva, {Svetlana E.} and Antipin, {Igor S.}",
year = "2019",
month = dec,
day = "1",
doi = "10.1007/s10967-019-06880-4",
language = "English",
volume = "322",
pages = "1931--1939",
journal = "Journal of Radioanalytical and Nuclear Chemistry",
issn = "0236-5731",
publisher = "Springer Nature",
number = "3",

}

RIS

TY - JOUR

T1 - γ-Radiolysis of functionalized calixarenes and its effect on cesium and americium extraction

AU - Smirnov, Igor V.

AU - Karavan, Maria D.

AU - Istomina, Natalya M.

AU - Misharev, Alexander D.

AU - Zaripov, Salavat R.

AU - Solovieva, Svetlana E.

AU - Antipin, Igor S.

PY - 2019/12/1

Y1 - 2019/12/1

N2 - The effect of γ-radiation on the extraction properties of two functionalized calixarenes (p-tert-butyl-thiacalix[4]arene and p-tert-butylcalix[8]arene) is studied. The most characteristic products of the irradiated extractants interaction with diluent are identified by mass spectrometry. Extraction ability of studied calixarenes towards cesium and americium before and after irradiation is evaluated. Quantitative analysis of chloride and sulfate ions after irradiation is performed to estimate the radiological degradation degree of components. Irradiation has different effect on p-tert-butyl-thiacalix[4]arene and p-tert-butylcalix[8]arene extraction ability towards americium, which may be due to the nature and extraction ability of radiolysis products, and practically does not affect cesium extraction.

AB - The effect of γ-radiation on the extraction properties of two functionalized calixarenes (p-tert-butyl-thiacalix[4]arene and p-tert-butylcalix[8]arene) is studied. The most characteristic products of the irradiated extractants interaction with diluent are identified by mass spectrometry. Extraction ability of studied calixarenes towards cesium and americium before and after irradiation is evaluated. Quantitative analysis of chloride and sulfate ions after irradiation is performed to estimate the radiological degradation degree of components. Irradiation has different effect on p-tert-butyl-thiacalix[4]arene and p-tert-butylcalix[8]arene extraction ability towards americium, which may be due to the nature and extraction ability of radiolysis products, and practically does not affect cesium extraction.

KW - Alkaline media

KW - Americium-241

KW - Cesium-137

KW - Functionalized calixarenes

KW - Radioactive waste

KW - Solvent extraction

KW - γ-Radiolysis

UR - http://www.scopus.com/inward/record.url?scp=85074756274&partnerID=8YFLogxK

U2 - 10.1007/s10967-019-06880-4

DO - 10.1007/s10967-019-06880-4

M3 - Article

AN - SCOPUS:85074756274

VL - 322

SP - 1931

EP - 1939

JO - Journal of Radioanalytical and Nuclear Chemistry

JF - Journal of Radioanalytical and Nuclear Chemistry

SN - 0236-5731

IS - 3

ER -

ID: 51527125