For the atmospheric layer between 30 and 170 km, the radiative heat influx in vibrational CO2 bands is refined. The refinement is based on (1) the most comprehensive model currently available for the system of vibrational states and corresponding optical transitions, (2) updated data on the rates of vibration-translation and vibration-vibration processes, and (3) a computational procedure providing a high accuracy of the results. For the rate of nighttime radiative cooling, two trends are revealed. (a) A significant increase in the rate of lower-thermosphere cooling is possible in the 15-μm band under consideration. This increase is due to collisions between CO2 molecules and O atoms, which are accompanied by multiquantum ν2-mode transitions. (b) The contribution of cooling in the 4.3-μm CO2 band reaches 0.2-0.35°C/day at the stratopause. For daytime conditions, the contribution of each individual CO2 band between 15 and 1.05 μm to the integral radiative heating in CO2 bands and the dependence of this heating on the solar zenith angle are studied. The parametrization of the rate of nighttime atmospheric radiative cooling in the 15-μm CO2 band is improved.

Язык оригиналаанглийский
Страницы (с-по)454-464
Число страниц11
ЖурналIzvestiya - Atmospheric and Ocean Physics
Том36
Номер выпуска4
СостояниеОпубликовано - 1 янв 2000

    Предметные области Scopus

  • Океанография
  • Наука об атмосфере

ID: 39862079