Standard

Quaternary liquid-liquid equilibrium, solubility and critical states: Acetic acid - n-butanol - n-butyl acetate - water at 318.15 K and atmospheric pressure. / Smirnov, Alexander; Sadaeva, Anna; Podryadova, Kristina; Toikka, Maria.

в: Fluid Phase Equilibria, Том 493, 01.08.2019, стр. 102-108.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Smirnov, A, Sadaeva, A, Podryadova, K & Toikka, M 2019, 'Quaternary liquid-liquid equilibrium, solubility and critical states: Acetic acid - n-butanol - n-butyl acetate - water at 318.15 K and atmospheric pressure', Fluid Phase Equilibria, Том. 493, стр. 102-108. https://doi.org/10.1016/j.fluid.2019.04.020

APA

Smirnov, A., Sadaeva, A., Podryadova, K., & Toikka, M. (2019). Quaternary liquid-liquid equilibrium, solubility and critical states: Acetic acid - n-butanol - n-butyl acetate - water at 318.15 K and atmospheric pressure. Fluid Phase Equilibria, 493, 102-108. https://doi.org/10.1016/j.fluid.2019.04.020

Vancouver

Smirnov A, Sadaeva A, Podryadova K, Toikka M. Quaternary liquid-liquid equilibrium, solubility and critical states: Acetic acid - n-butanol - n-butyl acetate - water at 318.15 K and atmospheric pressure. Fluid Phase Equilibria. 2019 Авг. 1;493:102-108. https://doi.org/10.1016/j.fluid.2019.04.020

Author

Smirnov, Alexander ; Sadaeva, Anna ; Podryadova, Kristina ; Toikka, Maria. / Quaternary liquid-liquid equilibrium, solubility and critical states: Acetic acid - n-butanol - n-butyl acetate - water at 318.15 K and atmospheric pressure. в: Fluid Phase Equilibria. 2019 ; Том 493. стр. 102-108.

BibTeX

@article{8e0481616df444c981c8d9b4be9241e2,
title = "Quaternary liquid-liquid equilibrium, solubility and critical states: Acetic acid - n-butanol - n-butyl acetate - water at 318.15 K and atmospheric pressure",
abstract = "Experimental data on solubility, critical states and liquid–liquid equilibrium (LLE) for the quaternary system acetic acid – n-butanol – n-butyl acetate – water and ternary subsystems acetic acid – n-butanol – water, n-butanol – n-butyl acetate – water and acetic acid – n-butyl acetate – water were obtained at 318.15 K and at atmospheric pressure. The solubility and critical states were studied by isothermal titration method (“cloud-point technique”). The LLE was determined using gas chromatographic analysis. Binodal surface in quaternary system and binodal curves in ternary systems were constructed. Compositions of critical points (plait points) and critical curve were determined. The NRTL model was applied to calculate the LLE data for the quaternary and ternary systems. The results of NRTL modeling are in good agreement with the experimental data.",
keywords = "Critical phenomena, Liquid-liquid equilibrium, Solubility, n-butyl acetate, ESTER, SYSTEM, PHASE, ALCOHOL, PROPIONATE-WATER, ETHYL-ACETATE, ETHANOL, PROPYL ACETATE, PROPANOL",
author = "Alexander Smirnov and Anna Sadaeva and Kristina Podryadova and Maria Toikka",
year = "2019",
month = aug,
day = "1",
doi = "10.1016/j.fluid.2019.04.020",
language = "English",
volume = "493",
pages = "102--108",
journal = "Fluid Phase Equilibria",
issn = "0378-3812",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Quaternary liquid-liquid equilibrium, solubility and critical states: Acetic acid - n-butanol - n-butyl acetate - water at 318.15 K and atmospheric pressure

AU - Smirnov, Alexander

AU - Sadaeva, Anna

AU - Podryadova, Kristina

AU - Toikka, Maria

PY - 2019/8/1

Y1 - 2019/8/1

N2 - Experimental data on solubility, critical states and liquid–liquid equilibrium (LLE) for the quaternary system acetic acid – n-butanol – n-butyl acetate – water and ternary subsystems acetic acid – n-butanol – water, n-butanol – n-butyl acetate – water and acetic acid – n-butyl acetate – water were obtained at 318.15 K and at atmospheric pressure. The solubility and critical states were studied by isothermal titration method (“cloud-point technique”). The LLE was determined using gas chromatographic analysis. Binodal surface in quaternary system and binodal curves in ternary systems were constructed. Compositions of critical points (plait points) and critical curve were determined. The NRTL model was applied to calculate the LLE data for the quaternary and ternary systems. The results of NRTL modeling are in good agreement with the experimental data.

AB - Experimental data on solubility, critical states and liquid–liquid equilibrium (LLE) for the quaternary system acetic acid – n-butanol – n-butyl acetate – water and ternary subsystems acetic acid – n-butanol – water, n-butanol – n-butyl acetate – water and acetic acid – n-butyl acetate – water were obtained at 318.15 K and at atmospheric pressure. The solubility and critical states were studied by isothermal titration method (“cloud-point technique”). The LLE was determined using gas chromatographic analysis. Binodal surface in quaternary system and binodal curves in ternary systems were constructed. Compositions of critical points (plait points) and critical curve were determined. The NRTL model was applied to calculate the LLE data for the quaternary and ternary systems. The results of NRTL modeling are in good agreement with the experimental data.

KW - Critical phenomena

KW - Liquid-liquid equilibrium

KW - Solubility

KW - n-butyl acetate

KW - ESTER

KW - SYSTEM

KW - PHASE

KW - ALCOHOL

KW - PROPIONATE-WATER

KW - ETHYL-ACETATE

KW - ETHANOL

KW - PROPYL ACETATE

KW - PROPANOL

UR - https://www.sciencedirect.com/science/article/pii/S0378381219301785?dgcid=author

UR - http://www.scopus.com/inward/record.url?scp=85064596113&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/quaternary-liquidliquid-equilibrium-solubility-critical-states-acetic-acid-nbutanol-nbutyl-acetate-w

U2 - 10.1016/j.fluid.2019.04.020

DO - 10.1016/j.fluid.2019.04.020

M3 - Article

VL - 493

SP - 102

EP - 108

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

SN - 0378-3812

ER -

ID: 41191992