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Proton mobility in Ruddlesden–Popper phase H 2 La 2 Ti 3 O 10 studied by 1 H NMR. / Shelyapina, M.G.; Nefedov, D.Y.; Kostromin, A.V.; Silyukov, O.I.; Zvereva, I.A.

в: Ceramics International, Том 45, № 5, 2019, стр. 5788-5795.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Shelyapina, M.G. ; Nefedov, D.Y. ; Kostromin, A.V. ; Silyukov, O.I. ; Zvereva, I.A. / Proton mobility in Ruddlesden–Popper phase H 2 La 2 Ti 3 O 10 studied by 1 H NMR. в: Ceramics International. 2019 ; Том 45, № 5. стр. 5788-5795.

BibTeX

@article{e92434a26e8142bb8b33ab7efb3ba24a,
title = "Proton mobility in Ruddlesden–Popper phase H 2 La 2 Ti 3 O 10 studied by 1 H NMR.",
abstract = "To study protons localization in H 1.83 K 0.17 La 2 Ti 3 O 10 ·0.17H 2 O and their motional characteristics, complementary Nuclear Magnetic Resonance (NMR) techniques have been applied. 1 H Magic Angle Spinning NMR evidences the presence of different proton containing species. By analyzing the temperature dependence of the 1 H MAS NMR spectrum we attribute the observed lines to interlayer H + in regular sites (isolated and in water rich environment), water protons and protons from various defects. The temperature behaviors of the spectral lines intensities and widths point out that intercalated water molecules are involved in translational motion that is confirmed by spin lattice relaxation rate (R 1 ) and spin-lattice relaxation rate in rotating frame (R 1ρ ) measurements. It has been shown that for a correct determination of the proton motional parameters the Kohlrausch-Williams-Watts cor",
author = "M.G. Shelyapina and D.Y. Nefedov and A.V. Kostromin and O.I. Silyukov and I.A. Zvereva",
year = "2019",
language = "English",
volume = "45",
pages = "5788--5795",
journal = "Ceramics International",
issn = "0272-8842",
publisher = "Elsevier",
number = "5",

}

RIS

TY - JOUR

T1 - Proton mobility in Ruddlesden–Popper phase H 2 La 2 Ti 3 O 10 studied by 1 H NMR.

AU - Shelyapina, M.G.

AU - Nefedov, D.Y.

AU - Kostromin, A.V.

AU - Silyukov, O.I.

AU - Zvereva, I.A.

PY - 2019

Y1 - 2019

N2 - To study protons localization in H 1.83 K 0.17 La 2 Ti 3 O 10 ·0.17H 2 O and their motional characteristics, complementary Nuclear Magnetic Resonance (NMR) techniques have been applied. 1 H Magic Angle Spinning NMR evidences the presence of different proton containing species. By analyzing the temperature dependence of the 1 H MAS NMR spectrum we attribute the observed lines to interlayer H + in regular sites (isolated and in water rich environment), water protons and protons from various defects. The temperature behaviors of the spectral lines intensities and widths point out that intercalated water molecules are involved in translational motion that is confirmed by spin lattice relaxation rate (R 1 ) and spin-lattice relaxation rate in rotating frame (R 1ρ ) measurements. It has been shown that for a correct determination of the proton motional parameters the Kohlrausch-Williams-Watts cor

AB - To study protons localization in H 1.83 K 0.17 La 2 Ti 3 O 10 ·0.17H 2 O and their motional characteristics, complementary Nuclear Magnetic Resonance (NMR) techniques have been applied. 1 H Magic Angle Spinning NMR evidences the presence of different proton containing species. By analyzing the temperature dependence of the 1 H MAS NMR spectrum we attribute the observed lines to interlayer H + in regular sites (isolated and in water rich environment), water protons and protons from various defects. The temperature behaviors of the spectral lines intensities and widths point out that intercalated water molecules are involved in translational motion that is confirmed by spin lattice relaxation rate (R 1 ) and spin-lattice relaxation rate in rotating frame (R 1ρ ) measurements. It has been shown that for a correct determination of the proton motional parameters the Kohlrausch-Williams-Watts cor

M3 - Article

VL - 45

SP - 5788

EP - 5795

JO - Ceramics International

JF - Ceramics International

SN - 0272-8842

IS - 5

ER -

ID: 78577658