Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Solubility of individual light fullerenes (C60 and C70) in n-heptane was measured in the ranges of pressure from 0.1 up to 110 MPa and temperature from 298.3 to 358.3 K. At 0.1 MPa, the solubility diagrams of the C60 – n-heptane, C70 – n-heptane binary systems consist of only one branch corresponding to crystallization of mono-solvated fullerenes – C60·C7H16 and C70·C7H16. The compositions of the solid crystalline solvates were determined by thermogravimetric analysis. Thermodynamic description of the temperature and pressure dependences of solubility was performed using the van-der-Waals differential equation. As a result, the changes of the isothermal compressibility, molar volume, isobaric heat capacity and molar entropy in the process of the light fullerenes dissolution with formation of infinitely diluted solution were calculated.
Язык оригинала | английский |
---|---|
Страницы (с-по) | 569-577 |
Число страниц | 9 |
Журнал | Journal of Molecular Liquids |
Том | 268 |
Дата раннего онлайн-доступа | 17 июл 2018 |
DOI | |
Состояние | Опубликовано - 15 окт 2018 |
ID: 35260258