Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Potential energy curves and dipole transition moments to the ground stat of the system Ar*(3p54s,3P,1P) + Ne. / Petsalakis, Ioannis D.; Buenker, Robert J.; Lieberman, Heinz Peter; Alekseyev, Aleksey B.; Devdariani, Alexander Z.; Theodorakopoulos, Giannoula.
в: Journal of Chemical Physics, Том 113, № 14, 08.10.2000, стр. 5812-5816.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Potential energy curves and dipole transition moments to the ground stat of the system Ar*(3p54s,3P,1P) + Ne
AU - Petsalakis, Ioannis D.
AU - Buenker, Robert J.
AU - Lieberman, Heinz Peter
AU - Alekseyev, Aleksey B.
AU - Devdariani, Alexander Z.
AU - Theodorakopoulos, Giannoula
PY - 2000/10/8
Y1 - 2000/10/8
N2 - Relativistic core-potential calculations have been carried out on ft states resulting from the interaction of Ar*(3p54s,3P, 1P) with ground state Ne atoms. The results yield the correct asymptotic limits for the atomic states of Ar while shallow minima (700-800 cm-1) at large internuclear distances, 7-8 bohr, are obtained for the excited states. Dipole transition moments between pairs of states have been calculated and strong radiative transitions are predicted from excited states to the ground state. The 1(1) state, correlating with the metastable 3P2 state of Ar is found to have a small dipole transition moment at short and intermediate nuclear distances leading to a radiative lifetime for this state of 8.3 μs.
AB - Relativistic core-potential calculations have been carried out on ft states resulting from the interaction of Ar*(3p54s,3P, 1P) with ground state Ne atoms. The results yield the correct asymptotic limits for the atomic states of Ar while shallow minima (700-800 cm-1) at large internuclear distances, 7-8 bohr, are obtained for the excited states. Dipole transition moments between pairs of states have been calculated and strong radiative transitions are predicted from excited states to the ground state. The 1(1) state, correlating with the metastable 3P2 state of Ar is found to have a small dipole transition moment at short and intermediate nuclear distances leading to a radiative lifetime for this state of 8.3 μs.
UR - http://www.scopus.com/inward/record.url?scp=0034299445&partnerID=8YFLogxK
M3 - Article
AN - SCOPUS:0034299445
VL - 113
SP - 5812
EP - 5816
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
SN - 0021-9606
IS - 14
ER -
ID: 28477659