TY - JOUR

T1 - Porous nickel deposits formed in the oxidation of alcohols in an alkaline medium

AU - Nikiforova, T.G.

AU - Stepanova, A.A.

AU - Datskevich, O.A.

AU - Malev, V.V.

PY - 2013

Y1 - 2013

N2 - Highly porous nickel matrices with varied content of nickel were formed on a glassy graphite electrode by the electrochemical deposition method. The nickel deposits were studied by pulsed chronoamperometry, impedance spectroscopy, and cyclic voltammetry on a rotating disk electrode in a 1 M KOH solution and in alkaline solutions containing methanol or ethanol. The process in which a hydroxide film is formed on the nickel surface in an alkaline solution and the influence exerted by this process on the catalytic oxidation of alcohols on nickel in an alkaline medium are discussed. © Pleiades Publishing, Ltd., 2013.

AB - Highly porous nickel matrices with varied content of nickel were formed on a glassy graphite electrode by the electrochemical deposition method. The nickel deposits were studied by pulsed chronoamperometry, impedance spectroscopy, and cyclic voltammetry on a rotating disk electrode in a 1 M KOH solution and in alkaline solutions containing methanol or ethanol. The process in which a hydroxide film is formed on the nickel surface in an alkaline solution and the influence exerted by this process on the catalytic oxidation of alcohols on nickel in an alkaline medium are discussed. © Pleiades Publishing, Ltd., 2013.

U2 - 10.1134/S107042721311013X

DO - 10.1134/S107042721311013X

M3 - Article

VL - 86

SP - 1713

EP - 1718

JO - Russian Journal of Applied Chemistry

JF - Russian Journal of Applied Chemistry

SN - 1070-4272

IS - 11

ER -