Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds

Standard

Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds. / Rozentsvet, V. A.; Ulyanova, D. M.; Sablina, N. A.; Kuznetsova, M. G.; Tolstoy, P. M.

в: Russian Chemical Bulletin, Том 71, № 4, 01.04.2022, стр. 787-795.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Author

Rozentsvet, V. A. ; Ulyanova, D. M. ; Sablina, N. A. ; Kuznetsova, M. G. ; Tolstoy, P. M. / Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds. в: Russian Chemical Bulletin. 2022 ; Том 71, № 4. стр. 787-795.

BibTeX

@article{1b4bea1b2646421e962bb70cb2efd6ba,

title = "Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds",

abstract = "Cationic polymerization of penta-1,3-diene with catalytic systems based on organoaluminum compounds (AlEtCl2, AlEt2Cl, and AlEt3) in combination with isopropyl chloride makes it possible to synthesize completely soluble solid polymers in a high yield with the softening point in the range from 81 to 91 °C. The signals of carbon atoms of the head isopropyl groups connected with 1,4-trans-unit of polypentadiene were identified using 1H and 13C NMR spectroscopy with the T2 filter, as well as 1H, 13C HSQC and HMBC 2D NMR spectroscopy.",

keywords = "cationic polymerization, isopropyl chloride, organoaluminum compounds, penta-1,3-diene, polymer softening point",

author = "Rozentsvet, {V. A.} and Ulyanova, {D. M.} and Sablina, {N. A.} and Kuznetsova, {M. G.} and Tolstoy, {P. M.}",

note = "Publisher Copyright: {\textcopyright} 2022, Springer Science+Business Media LLC.",

year = "2022",

month = apr,

day = "1",

doi = "10.1007/s11172-022-3479-1",

language = "English",

volume = "71",

pages = "787--795",

journal = "Russian Chemical Bulletin",

issn = "1066-5285",

publisher = "Springer Nature",

number = "4",

}

RIS

TY - JOUR

T1 - Polymerization of penta-1,3-diene using cationic catalytic systems based on organoaluminum compounds

AU - Rozentsvet, V. A.

AU - Ulyanova, D. M.

AU - Sablina, N. A.

AU - Kuznetsova, M. G.

AU - Tolstoy, P. M.

PY - 2022/4/1

Y1 - 2022/4/1

N2 - Cationic polymerization of penta-1,3-diene with catalytic systems based on organoaluminum compounds (AlEtCl2, AlEt2Cl, and AlEt3) in combination with isopropyl chloride makes it possible to synthesize completely soluble solid polymers in a high yield with the softening point in the range from 81 to 91 °C. The signals of carbon atoms of the head isopropyl groups connected with 1,4-trans-unit of polypentadiene were identified using 1H and 13C NMR spectroscopy with the T2 filter, as well as 1H, 13C HSQC and HMBC 2D NMR spectroscopy.

AB - Cationic polymerization of penta-1,3-diene with catalytic systems based on organoaluminum compounds (AlEtCl2, AlEt2Cl, and AlEt3) in combination with isopropyl chloride makes it possible to synthesize completely soluble solid polymers in a high yield with the softening point in the range from 81 to 91 °C. The signals of carbon atoms of the head isopropyl groups connected with 1,4-trans-unit of polypentadiene were identified using 1H and 13C NMR spectroscopy with the T2 filter, as well as 1H, 13C HSQC and HMBC 2D NMR spectroscopy.

KW - cationic polymerization

KW - isopropyl chloride

KW - organoaluminum compounds

KW - penta-1,3-diene

KW - polymer softening point

UR - http://www.scopus.com/inward/record.url?scp=85128871788&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/b3eb4205-8629-3dac-95bd-173bf79a9d47/

U2 - 10.1007/s11172-022-3479-1

DO - 10.1007/s11172-022-3479-1

M3 - Article

AN - SCOPUS:85128871788

VL - 71

SP - 787

EP - 795

JO - Russian Chemical Bulletin

JF - Russian Chemical Bulletin

SN - 1066-5285

IS - 4

ER -

ID: 99550238