Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Polymerization of Isoprene Using Cationic Catalytic Systems Based on Triethylaluminum. / Rozentsvet, V. A.; Sablina, N. A.; Ulyanova, D. M.; Tolstoy, P. M.; Novakov, I. A.
в: Doklady Physical Chemistry, Том 499, № 2, 08.2021, стр. 73-76.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
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TY - JOUR
T1 - Polymerization of Isoprene Using Cationic Catalytic Systems Based on Triethylaluminum
AU - Rozentsvet, V. A.
AU - Sablina, N. A.
AU - Ulyanova, D. M.
AU - Tolstoy, P. M.
AU - Novakov, I. A.
N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd.
PY - 2021/8
Y1 - 2021/8
N2 - Abstract: A new efficient method for the synthesis of soluble thermoplastic polymers of isoprene with softening points in the range from 73 to 160°C has been developed. The method consists in the cationic polymerization of isoprene in dichloromethane or toluene in the presence of catalytic systems based on triethylaluminum in combination with tert-butyl chloride, tert-butyl bromide, 2-chloro-2-methylbutane, or isopropyl chloride.
AB - Abstract: A new efficient method for the synthesis of soluble thermoplastic polymers of isoprene with softening points in the range from 73 to 160°C has been developed. The method consists in the cationic polymerization of isoprene in dichloromethane or toluene in the presence of catalytic systems based on triethylaluminum in combination with tert-butyl chloride, tert-butyl bromide, 2-chloro-2-methylbutane, or isopropyl chloride.
KW - alkyl halides
KW - cationic polymerization
KW - isoprene
KW - triethylaluminum
KW - INITIATION
KW - MODEL
KW - TERMINATION
UR - http://www.scopus.com/inward/record.url?scp=85120742613&partnerID=8YFLogxK
U2 - 10.1134/s0012501621080017
DO - 10.1134/s0012501621080017
M3 - Article
AN - SCOPUS:85120742613
VL - 499
SP - 73
EP - 76
JO - Doklady Physical Chemistry
JF - Doklady Physical Chemistry
SN - 0012-5016
IS - 2
ER -
ID: 89586139