DOI

Hydrogen bond patterns of crystals of phosphinic, phosphonic, and phosphoric acids and their cocrystals with phosphine oxides were studied using 31P NMR and single-crystal X-ray diffraction. Two main factors govern these patterns and favor or prevent the formation of cocrystals. The first one is a high proton-accepting ability of the P=O moiety in these acids. As a result, this moiety effectively competes with other proton acceptors for hydrogen bonding. For example, this moiety is a stronger proton acceptor than the C=O moiety of carboxylic acids. The second factor is the inclination of the P=O moiety of both the acids and the oxides to form two hydrogen bonds at once. The peculiarity of these bonds is that they weaken each other to a little degree only. In order to highlight this point, we are using the term "ambidextrous". These two features should govern the interactions of P=O moiety with water and other proton donors and acceptors in molecular clusters, the active sites of enzymes, soft matter, and at surfaces.

Язык оригиналаанглийский
Страницы (с-по)1711-1720
Число страниц10
ЖурналJournal of Physical Chemistry C
Том122
Номер выпуска3
DOI
СостояниеОпубликовано - 25 янв 2018

    Предметные области Scopus

  • Электроника, оптика и магнитные материалы
  • Энергия (все)
  • Поверхности, слои и пленки
  • Физическая и теоретическая химия

ID: 18466025