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Pnicogen and chalcogen bonds in cyclometalated iridium(III) complexes. / Kinzhalov, Mikhail A.; Popova, Ekaterina A.; Petrov, Mikhail L.; Khoroshilova, Olesya V.; Mahmudov, Kamran T.; Pombeiro, Armando J.L.

в: Inorganica Chimica Acta, Том 477, 24.05.2018, стр. 31-33.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Kinzhalov, MA, Popova, EA, Petrov, ML, Khoroshilova, OV, Mahmudov, KT & Pombeiro, AJL 2018, 'Pnicogen and chalcogen bonds in cyclometalated iridium(III) complexes', Inorganica Chimica Acta, Том. 477, стр. 31-33. https://doi.org/10.1016/j.ica.2018.02.029

APA

Kinzhalov, M. A., Popova, E. A., Petrov, M. L., Khoroshilova, O. V., Mahmudov, K. T., & Pombeiro, A. J. L. (2018). Pnicogen and chalcogen bonds in cyclometalated iridium(III) complexes. Inorganica Chimica Acta, 477, 31-33. https://doi.org/10.1016/j.ica.2018.02.029

Vancouver

Kinzhalov MA, Popova EA, Petrov ML, Khoroshilova OV, Mahmudov KT, Pombeiro AJL. Pnicogen and chalcogen bonds in cyclometalated iridium(III) complexes. Inorganica Chimica Acta. 2018 Май 24;477:31-33. https://doi.org/10.1016/j.ica.2018.02.029

Author

Kinzhalov, Mikhail A. ; Popova, Ekaterina A. ; Petrov, Mikhail L. ; Khoroshilova, Olesya V. ; Mahmudov, Kamran T. ; Pombeiro, Armando J.L. / Pnicogen and chalcogen bonds in cyclometalated iridium(III) complexes. в: Inorganica Chimica Acta. 2018 ; Том 477. стр. 31-33.

BibTeX

@article{fc0d7137455d4cb380ab63954aee0d3b,
title = "Pnicogen and chalcogen bonds in cyclometalated iridium(III) complexes",
abstract = "Reaction of organoiridium(III)-2-phenylpyridine complex, [Ir(ppy)2(μ-Cl)]2 (ppy = 2-phenylpyridinato-C2,N), with 4-(2-bromophenyl)-1,2,3-thiodiazole (X) or 4-(2-bromophenyl)-1,2,3-selenadiazole (Y) in CH2Cl2 yields to [Ir(ppy)2Cl(X)]·CH2Cl2 (1) or [Ir(ppy)2Cl(Y)] (2), respectively. Both compounds were characterized by characterized by elemental analyses (C, H, N), HRESI+-MS, FTIR, and studied by single-crystal X-ray diffraction. The coordination environment of the central iridium(III) has a distorted octahedral geometry, four sites being occupied by two (ppy)−, which chelates in the C,N fashion, while the two other sites are filled with the Cl− and X (or Y) ligands. The intramolecular S···N and Se···Cl types of chalcogen bonds were found in the structures of 1 and 2, respectively. Compound 1 is also present intramolecular pnicogen bonding and intermolecular halogen bonding (between CH2Cl2 molecules) with the short N···Br (3.160 {\AA}) and Cl···Cl (2.187 {\AA}) distances. The crystal structures in 1 and 2 are stabilized by medium-strong intermolecular hydrogen bonding interactions.",
keywords = "1,2,3-Selenadiazole, 1,2,3-Thiodiazole, Chalcogen bonding, Iridium(III) complexes, Pnicogen bonding",
author = "Kinzhalov, {Mikhail A.} and Popova, {Ekaterina A.} and Petrov, {Mikhail L.} and Khoroshilova, {Olesya V.} and Mahmudov, {Kamran T.} and Pombeiro, {Armando J.L.}",
year = "2018",
month = may,
day = "24",
doi = "10.1016/j.ica.2018.02.029",
language = "English",
volume = "477",
pages = "31--33",
journal = "Inorganica Chimica Acta",
issn = "0020-1693",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Pnicogen and chalcogen bonds in cyclometalated iridium(III) complexes

AU - Kinzhalov, Mikhail A.

AU - Popova, Ekaterina A.

AU - Petrov, Mikhail L.

AU - Khoroshilova, Olesya V.

AU - Mahmudov, Kamran T.

AU - Pombeiro, Armando J.L.

PY - 2018/5/24

Y1 - 2018/5/24

N2 - Reaction of organoiridium(III)-2-phenylpyridine complex, [Ir(ppy)2(μ-Cl)]2 (ppy = 2-phenylpyridinato-C2,N), with 4-(2-bromophenyl)-1,2,3-thiodiazole (X) or 4-(2-bromophenyl)-1,2,3-selenadiazole (Y) in CH2Cl2 yields to [Ir(ppy)2Cl(X)]·CH2Cl2 (1) or [Ir(ppy)2Cl(Y)] (2), respectively. Both compounds were characterized by characterized by elemental analyses (C, H, N), HRESI+-MS, FTIR, and studied by single-crystal X-ray diffraction. The coordination environment of the central iridium(III) has a distorted octahedral geometry, four sites being occupied by two (ppy)−, which chelates in the C,N fashion, while the two other sites are filled with the Cl− and X (or Y) ligands. The intramolecular S···N and Se···Cl types of chalcogen bonds were found in the structures of 1 and 2, respectively. Compound 1 is also present intramolecular pnicogen bonding and intermolecular halogen bonding (between CH2Cl2 molecules) with the short N···Br (3.160 Å) and Cl···Cl (2.187 Å) distances. The crystal structures in 1 and 2 are stabilized by medium-strong intermolecular hydrogen bonding interactions.

AB - Reaction of organoiridium(III)-2-phenylpyridine complex, [Ir(ppy)2(μ-Cl)]2 (ppy = 2-phenylpyridinato-C2,N), with 4-(2-bromophenyl)-1,2,3-thiodiazole (X) or 4-(2-bromophenyl)-1,2,3-selenadiazole (Y) in CH2Cl2 yields to [Ir(ppy)2Cl(X)]·CH2Cl2 (1) or [Ir(ppy)2Cl(Y)] (2), respectively. Both compounds were characterized by characterized by elemental analyses (C, H, N), HRESI+-MS, FTIR, and studied by single-crystal X-ray diffraction. The coordination environment of the central iridium(III) has a distorted octahedral geometry, four sites being occupied by two (ppy)−, which chelates in the C,N fashion, while the two other sites are filled with the Cl− and X (or Y) ligands. The intramolecular S···N and Se···Cl types of chalcogen bonds were found in the structures of 1 and 2, respectively. Compound 1 is also present intramolecular pnicogen bonding and intermolecular halogen bonding (between CH2Cl2 molecules) with the short N···Br (3.160 Å) and Cl···Cl (2.187 Å) distances. The crystal structures in 1 and 2 are stabilized by medium-strong intermolecular hydrogen bonding interactions.

KW - 1,2,3-Selenadiazole

KW - 1,2,3-Thiodiazole

KW - Chalcogen bonding

KW - Iridium(III) complexes

KW - Pnicogen bonding

UR - http://www.scopus.com/inward/record.url?scp=85044867214&partnerID=8YFLogxK

U2 - 10.1016/j.ica.2018.02.029

DO - 10.1016/j.ica.2018.02.029

M3 - Article

AN - SCOPUS:85044867214

VL - 477

SP - 31

EP - 33

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

SN - 0020-1693

ER -

ID: 46318133