Standard

Platinum-catalyzed reactions between Si-H groups as a new method for cross-linking of silicones. / Дерябин, Константин Валерьевич; Лобановская, Екатерина Константиновна; Новиков, Александр Сергеевич; Исламова, Регина Маратовна.

в: Organic and Biomolecular Chemistry, Том 17, № 22, 2019, стр. 5545-5549.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Дерябин, КВ, Лобановская, ЕК, Новиков, АС & Исламова, РМ 2019, 'Platinum-catalyzed reactions between Si-H groups as a new method for cross-linking of silicones', Organic and Biomolecular Chemistry, Том. 17, № 22, стр. 5545-5549. https://doi.org/10.1039/C9OB00791A

APA

Дерябин, К. В., Лобановская, Е. К., Новиков, А. С., & Исламова, Р. М. (2019). Platinum-catalyzed reactions between Si-H groups as a new method for cross-linking of silicones. Organic and Biomolecular Chemistry, 17(22), 5545-5549. https://doi.org/10.1039/C9OB00791A

Vancouver

Дерябин КВ, Лобановская ЕК, Новиков АС, Исламова РМ. Platinum-catalyzed reactions between Si-H groups as a new method for cross-linking of silicones. Organic and Biomolecular Chemistry. 2019;17(22):5545-5549. https://doi.org/10.1039/C9OB00791A

Author

Дерябин, Константин Валерьевич ; Лобановская, Екатерина Константиновна ; Новиков, Александр Сергеевич ; Исламова, Регина Маратовна. / Platinum-catalyzed reactions between Si-H groups as a new method for cross-linking of silicones. в: Organic and Biomolecular Chemistry. 2019 ; Том 17, № 22. стр. 5545-5549.

BibTeX

@article{c9790a58d3fe47ee8bc165445048d87e,
title = "Platinum-catalyzed reactions between Si-H groups as a new method for cross-linking of silicones",
abstract = "The platinum-catalyzed self-cross-linking of polymethylhydrosiloxane at RT in air was performed for the first time and proved by 1H, 13C, and 29Si SSNMR and swelling measurements. Quantum chemical modeling of possible structures was investigated. Platinum (0) and (ii) complexes were used as catalysts between the Si-H groups of polymethylhydrosiloxane. Karstedt's catalyst leads to Si-O-Si and Si-Si bond formation, but cis-[PtCl 2(BnCN) 2] generates predominantly Si-O-Si cross-links. cis-[PtCl 2(BnCN) 2] allows creating high-quality silicone rubbers without visible mechanical defects. This cross-linking approach can be used to obtain new Si-H-containing silicone materials. ",
keywords = "BOND METATHESIS MECHANISM, COMPLEXES, HYDROSILYLATION, POLYMERIZATION, POLYSILANES, SILANES, SILYL",
author = "Дерябин, {Константин Валерьевич} and Лобановская, {Екатерина Константиновна} and Новиков, {Александр Сергеевич} and Исламова, {Регина Маратовна}",
year = "2019",
doi = "10.1039/C9OB00791A",
language = "English",
volume = "17",
pages = "5545--5549",
journal = "Organic and Biomolecular Chemistry",
issn = "1477-0520",
publisher = "Royal Society of Chemistry",
number = "22",

}

RIS

TY - JOUR

T1 - Platinum-catalyzed reactions between Si-H groups as a new method for cross-linking of silicones

AU - Дерябин, Константин Валерьевич

AU - Лобановская, Екатерина Константиновна

AU - Новиков, Александр Сергеевич

AU - Исламова, Регина Маратовна

PY - 2019

Y1 - 2019

N2 - The platinum-catalyzed self-cross-linking of polymethylhydrosiloxane at RT in air was performed for the first time and proved by 1H, 13C, and 29Si SSNMR and swelling measurements. Quantum chemical modeling of possible structures was investigated. Platinum (0) and (ii) complexes were used as catalysts between the Si-H groups of polymethylhydrosiloxane. Karstedt's catalyst leads to Si-O-Si and Si-Si bond formation, but cis-[PtCl 2(BnCN) 2] generates predominantly Si-O-Si cross-links. cis-[PtCl 2(BnCN) 2] allows creating high-quality silicone rubbers without visible mechanical defects. This cross-linking approach can be used to obtain new Si-H-containing silicone materials.

AB - The platinum-catalyzed self-cross-linking of polymethylhydrosiloxane at RT in air was performed for the first time and proved by 1H, 13C, and 29Si SSNMR and swelling measurements. Quantum chemical modeling of possible structures was investigated. Platinum (0) and (ii) complexes were used as catalysts between the Si-H groups of polymethylhydrosiloxane. Karstedt's catalyst leads to Si-O-Si and Si-Si bond formation, but cis-[PtCl 2(BnCN) 2] generates predominantly Si-O-Si cross-links. cis-[PtCl 2(BnCN) 2] allows creating high-quality silicone rubbers without visible mechanical defects. This cross-linking approach can be used to obtain new Si-H-containing silicone materials.

KW - BOND METATHESIS MECHANISM

KW - COMPLEXES

KW - HYDROSILYLATION

KW - POLYMERIZATION

KW - POLYSILANES

KW - SILANES

KW - SILYL

UR - http://www.scopus.com/inward/record.url?scp=85066837363&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/platinumcatalyzed-reactions-between-sih-groups-new-method-crosslinking-silicones

U2 - 10.1039/C9OB00791A

DO - 10.1039/C9OB00791A

M3 - Article

VL - 17

SP - 5545

EP - 5549

JO - Organic and Biomolecular Chemistry

JF - Organic and Biomolecular Chemistry

SN - 1477-0520

IS - 22

ER -

ID: 41500281