Phosphorescent PtII Systems Featuring Both 2,2’-Dipyridylamine and 1,3,5-Triazapentadiene Ligands

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Phosphorescent PtII Systems Featuring Both 2,2’-Dipyridylamine and 1,3,5-Triazapentadiene Ligands. / Eliseev, Ivan I.; Gushchin, Pavel V.; Chen, Yi-An; Chou, Pi-Tai; Haukka, Matti; Starova, Galina L.; Kukushkin, Vadim Yu.

в: European Journal of Inorganic Chemistry, Том 2014, № 25, 2014, стр. 4101-4108.

Результаты исследований: Научные публикации в периодических изданиях › статья

BibTeX

@article{d783776d4b224e05abe257630367a9b1,

title = "Phosphorescent PtII Systems Featuring Both 2,2{\textquoteright}-Dipyridylamine and 1,3,5-Triazapentadiene Ligands",

abstract = "{\textcopyright} 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. The treatment of cis-[Pt(dpa)(RCN)2][SO3CF3]2 {dpa = 2,2′-dipyridylamine, R = Me, Et, CH2Ph, Ph; [2a-d](OTf)2} (OTf = SO3CF3) with 2 equiv. of N,N′-diphenylguanidine [NH=C(NHPh)2] in CH2Cl2 solutions at room temp. for 16 h gives [Pt(dpa){NH=C(R)NC(NHPh)=NPh}][SO3CF3] {[3a,b,d](OTf)} as the addition products and [Pt(dpa){NH=C(R)NHC(R)=NH}][SO3CF3]2 {[4a,b](OTf)2} as the tailoring products. The formulation of complexes [3a,b,d](OTf) and [4a,b](OTf)2 was supported by satisfactory C, H, and N elemental analyses and agreeable high-resolution ESI-MS, IR, and 1H (including 1H-1H COSY experiments) and 13C{1H} NMR data. The structures of all of the platinum species were determined by single-crystal X-ray diffraction. Th",

author = "Eliseev, {Ivan I.} and Gushchin, {Pavel V.} and Yi-An Chen and Pi-Tai Chou and Matti Haukka and Starova, {Galina L.} and Kukushkin, {Vadim Yu.}",

year = "2014",

doi = "10.1002/ejic.201402364",

language = "English",

volume = "2014",

pages = "4101--4108",

journal = "Berichte der deutschen chemischen Gesellschaft",

issn = "0365-9496",

publisher = "Wiley-Blackwell",

number = "25",

}

RIS

TY - JOUR

T1 - Phosphorescent PtII Systems Featuring Both 2,2’-Dipyridylamine and 1,3,5-Triazapentadiene Ligands

AU - Eliseev, Ivan I.

AU - Gushchin, Pavel V.

AU - Chen, Yi-An

AU - Chou, Pi-Tai

AU - Haukka, Matti

AU - Starova, Galina L.

AU - Kukushkin, Vadim Yu.

PY - 2014

Y1 - 2014

N2 - © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. The treatment of cis-[Pt(dpa)(RCN)2][SO3CF3]2 {dpa = 2,2′-dipyridylamine, R = Me, Et, CH2Ph, Ph; [2a-d](OTf)2} (OTf = SO3CF3) with 2 equiv. of N,N′-diphenylguanidine [NH=C(NHPh)2] in CH2Cl2 solutions at room temp. for 16 h gives [Pt(dpa){NH=C(R)NC(NHPh)=NPh}][SO3CF3] {[3a,b,d](OTf)} as the addition products and [Pt(dpa){NH=C(R)NHC(R)=NH}][SO3CF3]2 {[4a,b](OTf)2} as the tailoring products. The formulation of complexes [3a,b,d](OTf) and [4a,b](OTf)2 was supported by satisfactory C, H, and N elemental analyses and agreeable high-resolution ESI-MS, IR, and 1H (including 1H-1H COSY experiments) and 13C{1H} NMR data. The structures of all of the platinum species were determined by single-crystal X-ray diffraction. Th

AB - © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. The treatment of cis-[Pt(dpa)(RCN)2][SO3CF3]2 {dpa = 2,2′-dipyridylamine, R = Me, Et, CH2Ph, Ph; [2a-d](OTf)2} (OTf = SO3CF3) with 2 equiv. of N,N′-diphenylguanidine [NH=C(NHPh)2] in CH2Cl2 solutions at room temp. for 16 h gives [Pt(dpa){NH=C(R)NC(NHPh)=NPh}][SO3CF3] {[3a,b,d](OTf)} as the addition products and [Pt(dpa){NH=C(R)NHC(R)=NH}][SO3CF3]2 {[4a,b](OTf)2} as the tailoring products. The formulation of complexes [3a,b,d](OTf) and [4a,b](OTf)2 was supported by satisfactory C, H, and N elemental analyses and agreeable high-resolution ESI-MS, IR, and 1H (including 1H-1H COSY experiments) and 13C{1H} NMR data. The structures of all of the platinum species were determined by single-crystal X-ray diffraction. Th

U2 - 10.1002/ejic.201402364

DO - 10.1002/ejic.201402364

M3 - Article

VL - 2014

SP - 4101

EP - 4108

JO - Berichte der deutschen chemischen Gesellschaft

JF - Berichte der deutschen chemischen Gesellschaft

SN - 0365-9496

IS - 25

ER -

ID: 5709697