TY - GEN

T1 - Phase processes and critical states in reactive systems with liquid phase splitting: phase diagrams and thermodynamic peculiarities

AU - Toikka, Alexander

AU - Samarov, Artemiy

PY - 2014

Y1 - 2014

N2 - Peculiarities concerning phase diagrams and thermodynamic singularities of reacting systems with liquid phase splitting are considered. The main attention is given to the use of affinity for the complex thermodynamic and kinetic consideration of processes and equilibria in the systems with immiscibility area. The opportunities and advisability of the use chemical affinity for the analysis of separation and coupled processes in reacting media are considered. The inclusion in the analysis additional topological elements – stoichiometric lines, chemical equilibrium and iso-affinity curves, surfaces or hyper surfaces – leads to results that are useful for more precise characteristics of diagrams of heterogeneous reacting systems. The critical states in multicomponent reactive systems are discussed.

AB - Peculiarities concerning phase diagrams and thermodynamic singularities of reacting systems with liquid phase splitting are considered. The main attention is given to the use of affinity for the complex thermodynamic and kinetic consideration of processes and equilibria in the systems with immiscibility area. The opportunities and advisability of the use chemical affinity for the analysis of separation and coupled processes in reacting media are considered. The inclusion in the analysis additional topological elements – stoichiometric lines, chemical equilibrium and iso-affinity curves, surfaces or hyper surfaces – leads to results that are useful for more precise characteristics of diagrams of heterogeneous reacting systems. The critical states in multicomponent reactive systems are discussed.

M3 - статья в сборнике материалов конференции

SP - 46

EP - 50

BT - 10th International Conference Distillation & Absorption 2014. Book of full papers.

ER -