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This review is the first attempt to integrate the available data on all types of phase equilibria (solubility, extraction and sorption) in systems containing light fullerenes (C60 and C70). In the case of solubility diagrams, the following types of phase equilibria are considered: individual fullerene (C60 or C70) - solvent under polythermal and polybaric conditions; C60-C70 - solvent, individual fullerene - solvent(1) - solvent(2), as well as multicomponent systems comprising a single fullerene or an industrial mixture of fullerenes and vegetable oils, animal fats or essential oils under polythermal conditions. All published experimental data on the extraction equilibria in C60-C70 - liquid phase(1) - liquid phase(2) systems are described systematically and the sorption characteristics of various materials towards light fullerenes are estimated. The possibility of application of these experimental data for development of pre-chromatographic and chromatographic methods for separation of fullerene mixtures and application of fullerenes as nanomodifiers are described. The bibliography includes 87 references.

Переведенное названиеФазовые равновесия в системах, содержащих фуллерены как основа технологии получения и применения наноуглеродных материалов
Язык оригиналаанглийский
Страницы (с-по)38-59
Число страниц22
ЖурналRussian Chemical Reviews
Том85
Номер выпуска1
DOI
СостояниеОпубликовано - 2016

    Предметные области Scopus

  • Химия (все)

ID: 7546409