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Phase equilibria and thermodynamic properties of components in the Cs 2O-B2O3-SiO2 system at high temperatures. / Stolyarova, V. L.; Lopatin, S. I.; Belousova, O. L.; Grishchenko, L. V.

в: Glass Physics and Chemistry, Том 32, № 1, 01.01.2006, стр. 55-62.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Stolyarova, V. L. ; Lopatin, S. I. ; Belousova, O. L. ; Grishchenko, L. V. / Phase equilibria and thermodynamic properties of components in the Cs 2O-B2O3-SiO2 system at high temperatures. в: Glass Physics and Chemistry. 2006 ; Том 32, № 1. стр. 55-62.

BibTeX

@article{f897277e2dbf49cd841220821f2aad11,
title = "Phase equilibria and thermodynamic properties of components in the Cs 2O-B2O3-SiO2 system at high temperatures",
abstract = "The phase equilibria in the Cs2O-B2O 3-SiO2 system are investigated in the temperature range 873-1073 K by the annealing-quenching technique, high-temperature microscopy, and X-ray powder diffraction analysis. The vapor composition, the activities of the components, and the Gibbs energies of glasses and melts in the Cs 2O-B2O3-SiO2 system are determined at a temperature of 1020 K. It is demonstrated that glasses and melts in the Cs2O • B2O3-Cs2O • SiO2 system are characterized by positive deviations of the CsBO 2 activities and negative deviations of the Cs2O • SiO2 activities from ideal behavior. As a consequence, the deviations of the Gibbs energies from ideal behavior change their sign.",
author = "Stolyarova, {V. L.} and Lopatin, {S. I.} and Belousova, {O. L.} and Grishchenko, {L. V.}",
year = "2006",
month = jan,
day = "1",
doi = "10.1134/S108765960601007X",
language = "English",
volume = "32",
pages = "55--62",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "1",

}

RIS

TY - JOUR

T1 - Phase equilibria and thermodynamic properties of components in the Cs 2O-B2O3-SiO2 system at high temperatures

AU - Stolyarova, V. L.

AU - Lopatin, S. I.

AU - Belousova, O. L.

AU - Grishchenko, L. V.

PY - 2006/1/1

Y1 - 2006/1/1

N2 - The phase equilibria in the Cs2O-B2O 3-SiO2 system are investigated in the temperature range 873-1073 K by the annealing-quenching technique, high-temperature microscopy, and X-ray powder diffraction analysis. The vapor composition, the activities of the components, and the Gibbs energies of glasses and melts in the Cs 2O-B2O3-SiO2 system are determined at a temperature of 1020 K. It is demonstrated that glasses and melts in the Cs2O • B2O3-Cs2O • SiO2 system are characterized by positive deviations of the CsBO 2 activities and negative deviations of the Cs2O • SiO2 activities from ideal behavior. As a consequence, the deviations of the Gibbs energies from ideal behavior change their sign.

AB - The phase equilibria in the Cs2O-B2O 3-SiO2 system are investigated in the temperature range 873-1073 K by the annealing-quenching technique, high-temperature microscopy, and X-ray powder diffraction analysis. The vapor composition, the activities of the components, and the Gibbs energies of glasses and melts in the Cs 2O-B2O3-SiO2 system are determined at a temperature of 1020 K. It is demonstrated that glasses and melts in the Cs2O • B2O3-Cs2O • SiO2 system are characterized by positive deviations of the CsBO 2 activities and negative deviations of the Cs2O • SiO2 activities from ideal behavior. As a consequence, the deviations of the Gibbs energies from ideal behavior change their sign.

UR - http://www.scopus.com/inward/record.url?scp=33644953614&partnerID=8YFLogxK

U2 - 10.1134/S108765960601007X

DO - 10.1134/S108765960601007X

M3 - Article

AN - SCOPUS:33644953614

VL - 32

SP - 55

EP - 62

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 1

ER -

ID: 52739562