TY - JOUR

T1 - Peroxide route to the synthesis of ultrafine CeO 2 -Fe 2 O 3 nanocomposite via successive ionic layer deposition

AU - Popkov, V. I.

AU - Tolstoy, V. P.

AU - Nevedomskiy, V. N.

PY - 2019/3/1

Y1 - 2019/3/1

N2 - An ultrafine α-CeO 2 –α-Fe 2 O 3 nanocomposite was prepared from the ultradispersed nanoparticles of cerium (IV) and iron (III) amorphous hydroxides heat-treated at 600 °С and 900 °С in the air. The initial composites were obtained by the successive ionic layer deposition (SILD) method. According to scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and powder X-ray diffraction (PXRD), the cerium/iron ratio in the synthesized nanocomposite is close to 1:2, and the α-CeO 2 and α-Fe 2 O 3 nanocrystals are isometrically shaped and have an average size of 4 ± 1 and 7 ± 1 nm (600 °С) and 24 ± 2 and 35 ± 3 nm (900 °С), respectively. Transmission electron microscopy (TEM) and selected area electron diffraction (SAED) have shown that nanocrystals are evenly distributed in the composite volume and are spatially conjugated. The formation mechanisms of both initial amorphous composites of cerium (IV) and iron (III) hydroxides and of α-CeO 2 and α-Fe 2 O 3 nanocrystals were established. It was shown that synthesis of the initial hydroxide composite using the SILD method proceeds via the formation of amorphous cerium hydroxo-peroxide (CeO(OOH) 2 ). As a result of the study, a schematic mechanism for the formation of a composite based on ultrafine nanocrystals of cerium (IV) and iron (III) oxides has been proposed.

AB - An ultrafine α-CeO 2 –α-Fe 2 O 3 nanocomposite was prepared from the ultradispersed nanoparticles of cerium (IV) and iron (III) amorphous hydroxides heat-treated at 600 °С and 900 °С in the air. The initial composites were obtained by the successive ionic layer deposition (SILD) method. According to scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDX) and powder X-ray diffraction (PXRD), the cerium/iron ratio in the synthesized nanocomposite is close to 1:2, and the α-CeO 2 and α-Fe 2 O 3 nanocrystals are isometrically shaped and have an average size of 4 ± 1 and 7 ± 1 nm (600 °С) and 24 ± 2 and 35 ± 3 nm (900 °С), respectively. Transmission electron microscopy (TEM) and selected area electron diffraction (SAED) have shown that nanocrystals are evenly distributed in the composite volume and are spatially conjugated. The formation mechanisms of both initial amorphous composites of cerium (IV) and iron (III) hydroxides and of α-CeO 2 and α-Fe 2 O 3 nanocrystals were established. It was shown that synthesis of the initial hydroxide composite using the SILD method proceeds via the formation of amorphous cerium hydroxo-peroxide (CeO(OOH) 2 ). As a result of the study, a schematic mechanism for the formation of a composite based on ultrafine nanocrystals of cerium (IV) and iron (III) oxides has been proposed.

KW - Inorganic chemistry

KW - Materials chemistry

KW - Materials science

KW - Nanotechnology

KW - Physical chemistry

KW - NANOLAYERS

KW - OXIDATION

KW - PERFORMANCE

KW - IRON

KW - ADSORPTION

KW - HYDROGEN

KW - FLUORIDE REMOVAL

KW - OXYGEN CARRIER

KW - ADSORBENT

KW - CERIUM OXIDE

UR - http://www.scopus.com/inward/record.url?scp=85063395241&partnerID=8YFLogxK

U2 - 10.1016/j.heliyon.2019.e01443

DO - 10.1016/j.heliyon.2019.e01443

M3 - Article

AN - SCOPUS:85063395241

VL - 5

JO - Heliyon

JF - Heliyon

SN - 2405-8440

IS - 3

M1 - e01443

ER -