DOI

Melting and crystallization of n-decane embedded into porous glass with the mean pore size of about 6.4 nm were studied using acoustic and DSC methods. Smearing of the phase transitions, decrease of melting and freezing temperatures, pronounced hysteresis between melting and crystallization were revealed by both methods. In DSC measurements for the pore filling factors 70% and higher double peaks were observed upon cooling while only single peaks were present upon heating. Also a high reduction of the corresponding phase transition heats was revealed. Melting and freezing intervals determined by acoustic and DSC methods strongly differed from each other. A model which qualitatively explains the observed anomalies is proposed. It supposes the formation of liquid layers on the surface of the pores.

Переведенное названиеОсобенности плавления и кристаллизации Н-декана в пористом стекле
Язык оригиналаанглийский
Номер статьи125872
Число страниц7
ЖурналPhysics Letters A
Том383
Номер выпуска30
Дата раннего онлайн-доступа7 авг 2019
DOI
СостояниеОпубликовано - 25 окт 2019

    Предметные области Scopus

  • Физика и астрономия (все)

    Области исследований

  • лавление и кристаллизация в нанопорахн-деканПористое стеклоИмпульсно-фазовый ультразвуковой способДифференциальная сканирующая калориметрияРазмерный эффект

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