Standard

Peculiarities of Chemical Equilibria in Acetic Acid– n -Butyl Alcohol– n -Butyl Acetate–Water System at 318.15 K and 101.3 kPa. / Toikka, Maria; Smirnov, Alexander; Trofimova, Maya; Golikova, Alexandra; Prikhodko, Igor; Samarov, Artemiy; Toikka, Alexander.

в: Journal of Chemical & Engineering Data, Том 68, № 5, 25.04.2023, стр. 1145-1153.

Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование

Harvard

Toikka, M, Smirnov, A, Trofimova, M, Golikova, A, Prikhodko, I, Samarov, A & Toikka, A 2023, 'Peculiarities of Chemical Equilibria in Acetic Acid– n -Butyl Alcohol– n -Butyl Acetate–Water System at 318.15 K and 101.3 kPa', Journal of Chemical & Engineering Data, Том. 68, № 5, стр. 1145-1153. https://doi.org/10.1021/acs.jced.3c00009

APA

Toikka, M., Smirnov, A., Trofimova, M., Golikova, A., Prikhodko, I., Samarov, A., & Toikka, A. (2023). Peculiarities of Chemical Equilibria in Acetic Acid– n -Butyl Alcohol– n -Butyl Acetate–Water System at 318.15 K and 101.3 kPa. Journal of Chemical & Engineering Data, 68(5), 1145-1153. https://doi.org/10.1021/acs.jced.3c00009

Vancouver

Toikka M, Smirnov A, Trofimova M, Golikova A, Prikhodko I, Samarov A и пр. Peculiarities of Chemical Equilibria in Acetic Acid– n -Butyl Alcohol– n -Butyl Acetate–Water System at 318.15 K and 101.3 kPa. Journal of Chemical & Engineering Data. 2023 Апр. 25;68(5):1145-1153. https://doi.org/10.1021/acs.jced.3c00009

Author

Toikka, Maria ; Smirnov, Alexander ; Trofimova, Maya ; Golikova, Alexandra ; Prikhodko, Igor ; Samarov, Artemiy ; Toikka, Alexander. / Peculiarities of Chemical Equilibria in Acetic Acid– n -Butyl Alcohol– n -Butyl Acetate–Water System at 318.15 K and 101.3 kPa. в: Journal of Chemical & Engineering Data. 2023 ; Том 68, № 5. стр. 1145-1153.

BibTeX

@article{5e7967e137124838b4c9d5976f999d32,
title = "Peculiarities of Chemical Equilibria in Acetic Acid– n -Butyl Alcohol– n -Butyl Acetate–Water System at 318.15 K and 101.3 kPa",
abstract = "The study of chemical equilibria for the acetic acid-n-butyl alcohol-n-butyl acetate-water system at 318.15 K and 101.3 kPa is presented. New experimental data are obtained for chemically equilibrium states in homogeneous and heterogeneous regions with the use of gas chromatography analysis. Critical states corresponding to chemically equilibrium regions are discussed. All results are displayed on concentration diagrams in 3D and 2D versions (using variables α). As a result of comparing the obtained results with the literature data, the corresponding conclusions were drawn. For the correlation of experimental data, the model NRTL was applied. The analysis and calculation of concentration and thermodynamic equilibrium constants have been carried out. The model UNIFAC was used to calculate the thermodynamic constant.",
author = "Maria Toikka and Alexander Smirnov and Maya Trofimova and Alexandra Golikova and Igor Prikhodko and Artemiy Samarov and Alexander Toikka",
year = "2023",
month = apr,
day = "25",
doi = "10.1021/acs.jced.3c00009",
language = "English",
volume = "68",
pages = "1145--1153",
journal = "Journal of Chemical & Engineering Data",
issn = "0021-9568",
publisher = "American Chemical Society",
number = "5",

}

RIS

TY - JOUR

T1 - Peculiarities of Chemical Equilibria in Acetic Acid– n -Butyl Alcohol– n -Butyl Acetate–Water System at 318.15 K and 101.3 kPa

AU - Toikka, Maria

AU - Smirnov, Alexander

AU - Trofimova, Maya

AU - Golikova, Alexandra

AU - Prikhodko, Igor

AU - Samarov, Artemiy

AU - Toikka, Alexander

PY - 2023/4/25

Y1 - 2023/4/25

N2 - The study of chemical equilibria for the acetic acid-n-butyl alcohol-n-butyl acetate-water system at 318.15 K and 101.3 kPa is presented. New experimental data are obtained for chemically equilibrium states in homogeneous and heterogeneous regions with the use of gas chromatography analysis. Critical states corresponding to chemically equilibrium regions are discussed. All results are displayed on concentration diagrams in 3D and 2D versions (using variables α). As a result of comparing the obtained results with the literature data, the corresponding conclusions were drawn. For the correlation of experimental data, the model NRTL was applied. The analysis and calculation of concentration and thermodynamic equilibrium constants have been carried out. The model UNIFAC was used to calculate the thermodynamic constant.

AB - The study of chemical equilibria for the acetic acid-n-butyl alcohol-n-butyl acetate-water system at 318.15 K and 101.3 kPa is presented. New experimental data are obtained for chemically equilibrium states in homogeneous and heterogeneous regions with the use of gas chromatography analysis. Critical states corresponding to chemically equilibrium regions are discussed. All results are displayed on concentration diagrams in 3D and 2D versions (using variables α). As a result of comparing the obtained results with the literature data, the corresponding conclusions were drawn. For the correlation of experimental data, the model NRTL was applied. The analysis and calculation of concentration and thermodynamic equilibrium constants have been carried out. The model UNIFAC was used to calculate the thermodynamic constant.

UR - https://www.mendeley.com/catalogue/2791ab70-d244-3bf5-bda6-cb4cccf551b9/

U2 - 10.1021/acs.jced.3c00009

DO - 10.1021/acs.jced.3c00009

M3 - Article

VL - 68

SP - 1145

EP - 1153

JO - Journal of Chemical & Engineering Data

JF - Journal of Chemical & Engineering Data

SN - 0021-9568

IS - 5

ER -

ID: 105124649