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Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases. / Novozhilova, M. V.; Danilova, Yu S.; Karushev, M. P.; Timonov, A. M.; Malev, V. V.; Levin, O. V.

в: Russian Journal of Electrochemistry, Том 54, № 10, 01.10.2018, стр. 769-774.

Результаты исследований: Научные публикации в периодических изданияхстатьяРецензирование

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Author

Novozhilova, M. V. ; Danilova, Yu S. ; Karushev, M. P. ; Timonov, A. M. ; Malev, V. V. ; Levin, O. V. / Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases. в: Russian Journal of Electrochemistry. 2018 ; Том 54, № 10. стр. 769-774.

BibTeX

@article{db88fd4a667444d79077f5f70535cea1,
title = "Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases",
abstract = "In energy-storage systems such as fuel cells and metal-air batteries, the main current-forming process is the reaction of oxygen electroreduction (OER). A simple method is proposed for synthesizing OER catalysts based on polymer complexes of transition metals (nickel, palladium) with Schiff bases prepared by electrochemical polymerization of starting monomers. The OER catalysts are prepared by thermolysis of polymers in inert atmosphere. Their properties are characterized by the methods of cyclic voltammetry with the use of a rotating disk electrode. The surface state (the catalyst film density, the size and composition of particles) is controlled by scanning electron microscopy with X-ray microanalysis. The electrode demonstrates the high catalytic activity in the oxygen electroreduction reaction in alkaline solutions (higher than 750 mA/mg of the initial polymer mass).",
keywords = "conducting polymer-metal complexes, fuel cells, metal-air batteries, oxygen electroreduction",
author = "Novozhilova, {M. V.} and Danilova, {Yu S.} and Karushev, {M. P.} and Timonov, {A. M.} and Malev, {V. V.} and Levin, {O. V.}",
year = "2018",
month = oct,
day = "1",
doi = "10.1134/S102319351810004X",
language = "English",
volume = "54",
pages = "769--774",
journal = "Russian Journal of Electrochemistry",
issn = "1023-1935",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "10",

}

RIS

TY - JOUR

T1 - Oxygen Electroreduction Catalysts Based on Polymer Complexes of Nickel with Schiff Bases

AU - Novozhilova, M. V.

AU - Danilova, Yu S.

AU - Karushev, M. P.

AU - Timonov, A. M.

AU - Malev, V. V.

AU - Levin, O. V.

PY - 2018/10/1

Y1 - 2018/10/1

N2 - In energy-storage systems such as fuel cells and metal-air batteries, the main current-forming process is the reaction of oxygen electroreduction (OER). A simple method is proposed for synthesizing OER catalysts based on polymer complexes of transition metals (nickel, palladium) with Schiff bases prepared by electrochemical polymerization of starting monomers. The OER catalysts are prepared by thermolysis of polymers in inert atmosphere. Their properties are characterized by the methods of cyclic voltammetry with the use of a rotating disk electrode. The surface state (the catalyst film density, the size and composition of particles) is controlled by scanning electron microscopy with X-ray microanalysis. The electrode demonstrates the high catalytic activity in the oxygen electroreduction reaction in alkaline solutions (higher than 750 mA/mg of the initial polymer mass).

AB - In energy-storage systems such as fuel cells and metal-air batteries, the main current-forming process is the reaction of oxygen electroreduction (OER). A simple method is proposed for synthesizing OER catalysts based on polymer complexes of transition metals (nickel, palladium) with Schiff bases prepared by electrochemical polymerization of starting monomers. The OER catalysts are prepared by thermolysis of polymers in inert atmosphere. Their properties are characterized by the methods of cyclic voltammetry with the use of a rotating disk electrode. The surface state (the catalyst film density, the size and composition of particles) is controlled by scanning electron microscopy with X-ray microanalysis. The electrode demonstrates the high catalytic activity in the oxygen electroreduction reaction in alkaline solutions (higher than 750 mA/mg of the initial polymer mass).

KW - conducting polymer-metal complexes

KW - fuel cells

KW - metal-air batteries

KW - oxygen electroreduction

UR - http://www.scopus.com/inward/record.url?scp=85056904926&partnerID=8YFLogxK

U2 - 10.1134/S102319351810004X

DO - 10.1134/S102319351810004X

M3 - Article

AN - SCOPUS:85056904926

VL - 54

SP - 769

EP - 774

JO - Russian Journal of Electrochemistry

JF - Russian Journal of Electrochemistry

SN - 1023-1935

IS - 10

ER -

ID: 36236029