Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
Oxochloroselenate(IV) with Incorporated {Cl2} : The Case of Strong Cl⋅⋅⋅Cl Halogen Bonding. / Usoltsev, Andrey N.; Korobeynikov, Nikita A.; Kolesov, Boris A.; Novikov, Alexander S.; Abramov, Pavel A.; Sokolov, Maxim N.; Adonin, Sergey A.
в: Chemistry - A European Journal, Том 27, № 36, 25.06.2021, стр. 9292-9294.Результаты исследований: Научные публикации в периодических изданиях › статья › Рецензирование
}
TY - JOUR
T1 - Oxochloroselenate(IV) with Incorporated {Cl2}
T2 - The Case of Strong Cl⋅⋅⋅Cl Halogen Bonding
AU - Usoltsev, Andrey N.
AU - Korobeynikov, Nikita A.
AU - Kolesov, Boris A.
AU - Novikov, Alexander S.
AU - Abramov, Pavel A.
AU - Sokolov, Maxim N.
AU - Adonin, Sergey A.
N1 - Publisher Copyright: © 2021 Wiley-VCH GmbH Copyright: Copyright 2021 Elsevier B.V., All rights reserved.
PY - 2021/6/25
Y1 - 2021/6/25
N2 - Reaction of SeO2, tetramethylammonium (TMA) chloride, aqueous HCl and Cl2 yields oxochloroselenate with incorporated Cl2 units, TMA3{[Se2O2Cl7](Cl2)}. The main feature of this compound is the strong (up to 3.5 kcal mol−1, according to DFT calculations) Cl⋅⋅⋅Cl bonding, which is also detected by Raman spectroscopy.
AB - Reaction of SeO2, tetramethylammonium (TMA) chloride, aqueous HCl and Cl2 yields oxochloroselenate with incorporated Cl2 units, TMA3{[Se2O2Cl7](Cl2)}. The main feature of this compound is the strong (up to 3.5 kcal mol−1, according to DFT calculations) Cl⋅⋅⋅Cl bonding, which is also detected by Raman spectroscopy.
KW - dichlorine
KW - halides
KW - halogen bonding
KW - noncovalent interactions
KW - selenium
KW - PHENYLTRIMETHYLAMMONIUM SALTS
KW - ANIONS
KW - OXOTRIHALOGENOSELENATES(IV)
KW - CRYSTAL-STRUCTURE
KW - COMPLEXES
KW - NONABROMOANTIMONATE(V)
KW - NONCOVALENT INTERACTIONS
KW - MONOANIONS
KW - BROMINE
KW - CENTER-DOT
UR - http://www.scopus.com/inward/record.url?scp=85106311802&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/60c1b042-664b-3874-ab63-1da8f7914cbe/
U2 - 10.1002/chem.202101024
DO - 10.1002/chem.202101024
M3 - Article
AN - SCOPUS:85106311802
VL - 27
SP - 9292
EP - 9294
JO - Chemistry - A European Journal
JF - Chemistry - A European Journal
SN - 0947-6539
IS - 36
ER -
ID: 77245150